Azafulvenium methides: new extended dipolar systems

O B Sutcliffe, R C Storr, T L Gilchrist, P Rafferty, A P A Crew

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

The transient 8 pi 1,7-dipolar azafulvenium methides 5 and 8 undergo sigmatropic [1,8] H shifts and the acyl derivatives 12 electrocyclise to give novel pyrrolooxazines 13; the related diazafulvenium methide 15 can be intercepted in 8 pi + 2 pi cycloadditions with silylated acetylenes.

LanguageEnglish
Pages675-676
Number of pages2
JournalChemical Communications (London)
Issue number8
Early online date30 Mar 2000
DOIs
Publication statusPublished - 2000

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Alkynes
Cycloaddition
Derivatives

Keywords

  • parameters
  • silylated acetylenes

Cite this

Sutcliffe, O. B., Storr, R. C., Gilchrist, T. L., Rafferty, P., & Crew, A. P. A. (2000). Azafulvenium methides: new extended dipolar systems. Chemical Communications (London), (8), 675-676. https://doi.org/10.1039/B001521K
Sutcliffe, O B ; Storr, R C ; Gilchrist, T L ; Rafferty, P ; Crew, A P A . / Azafulvenium methides : new extended dipolar systems. In: Chemical Communications (London). 2000 ; No. 8. pp. 675-676.
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Sutcliffe, OB, Storr, RC, Gilchrist, TL, Rafferty, P & Crew, APA 2000, 'Azafulvenium methides: new extended dipolar systems' Chemical Communications (London), no. 8, pp. 675-676. https://doi.org/10.1039/B001521K

Azafulvenium methides : new extended dipolar systems. / Sutcliffe, O B ; Storr, R C ; Gilchrist, T L ; Rafferty, P ; Crew, A P A .

In: Chemical Communications (London), No. 8, 2000, p. 675-676.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Azafulvenium methides

T2 - Chemical Communications (London)

AU - Sutcliffe, O B

AU - Storr, R C

AU - Gilchrist, T L

AU - Rafferty, P

AU - Crew, A P A

PY - 2000

Y1 - 2000

N2 - The transient 8 pi 1,7-dipolar azafulvenium methides 5 and 8 undergo sigmatropic [1,8] H shifts and the acyl derivatives 12 electrocyclise to give novel pyrrolooxazines 13; the related diazafulvenium methide 15 can be intercepted in 8 pi + 2 pi cycloadditions with silylated acetylenes.

AB - The transient 8 pi 1,7-dipolar azafulvenium methides 5 and 8 undergo sigmatropic [1,8] H shifts and the acyl derivatives 12 electrocyclise to give novel pyrrolooxazines 13; the related diazafulvenium methide 15 can be intercepted in 8 pi + 2 pi cycloadditions with silylated acetylenes.

KW - parameters

KW - silylated acetylenes

U2 - 10.1039/B001521K

DO - 10.1039/B001521K

M3 - Article

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EP - 676

JO - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

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Sutcliffe OB, Storr RC, Gilchrist TL, Rafferty P, Crew APA. Azafulvenium methides: new extended dipolar systems. Chemical Communications (London). 2000;(8):675-676. https://doi.org/10.1039/B001521K