Azafulvenium methides: new extended dipolar systems

O B  Sutcliffe; R C  Storr; T L  Gilchrist; P  Rafferty; A P A  Crew

doi:10.1039/B001521K

Azafulvenium methides: new extended dipolar systems

O B Sutcliffe, R C Storr, T L Gilchrist, P Rafferty, A P A Crew

Strathclyde Institute Of Pharmacy And Biomedical Sciences

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

The transient 8 pi 1,7-dipolar azafulvenium methides 5 and 8 undergo sigmatropic [1,8] H shifts and the acyl derivatives 12 electrocyclise to give novel pyrrolooxazines 13; the related diazafulvenium methide 15 can be intercepted in 8 pi + 2 pi cycloadditions with silylated acetylenes.

Original language	English
Pages (from-to)	675-676
Number of pages	2
Journal	Chemical Communications (London)
Issue number	8
Early online date	30 Mar 2000
DOIs	https://doi.org/10.1039/B001521K
Publication status	Published - 2000

Keywords

parameters
silylated acetylenes

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10.1039/B001521K

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title = "Azafulvenium methides: new extended dipolar systems",

abstract = "The transient 8 pi 1,7-dipolar azafulvenium methides 5 and 8 undergo sigmatropic [1,8] H shifts and the acyl derivatives 12 electrocyclise to give novel pyrrolooxazines 13; the related diazafulvenium methide 15 can be intercepted in 8 pi + 2 pi cycloadditions with silylated acetylenes.",

keywords = "parameters, silylated acetylenes",

author = "Sutcliffe, {O B} and Storr, {R C} and Gilchrist, {T L} and P Rafferty and Crew, {A P A}",

year = "2000",

doi = "10.1039/B001521K",

language = "English",

pages = "675--676",

journal = "Chemical Communications (London)",

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publisher = "Royal Society of Chemistry",

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T1 - Azafulvenium methides

T2 - new extended dipolar systems

AU - Sutcliffe, O B

AU - Storr, R C

AU - Gilchrist, T L

AU - Rafferty, P

AU - Crew, A P A

PY - 2000

Y1 - 2000

N2 - The transient 8 pi 1,7-dipolar azafulvenium methides 5 and 8 undergo sigmatropic [1,8] H shifts and the acyl derivatives 12 electrocyclise to give novel pyrrolooxazines 13; the related diazafulvenium methide 15 can be intercepted in 8 pi + 2 pi cycloadditions with silylated acetylenes.

AB - The transient 8 pi 1,7-dipolar azafulvenium methides 5 and 8 undergo sigmatropic [1,8] H shifts and the acyl derivatives 12 electrocyclise to give novel pyrrolooxazines 13; the related diazafulvenium methide 15 can be intercepted in 8 pi + 2 pi cycloadditions with silylated acetylenes.

KW - parameters

KW - silylated acetylenes

U2 - 10.1039/B001521K

DO - 10.1039/B001521K

M3 - Article

SN - 0009-241X

SP - 675

EP - 676

JO - Chemical Communications (London)

JF - Chemical Communications (London)

IS - 8

ER -

Azafulvenium methides: new extended dipolar systems

Abstract

Keywords

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