Atom-efficient synthesis of a benchmark electrolyte for magnesium battery applications

Scott A. Brown, Serena A. Cussen, Rhiannon Kennard, Sofia Marchesini, Jethro J. Pryke, Annabel Rae, Stuart D. Robertson, Rudra N. Samajdar, Andrew J. Wain

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)
21 Downloads (Pure)

Abstract

The benchmark magnesium electrolyte, [Mg2Cl3]+ [AlPh4]−, can be prepared in a 100% atom-economic fashion by a ligand exchange reaction between AlCl3 and two molar equivalents of MgPh2. NMR and vibrational spectroscopy indicate that the reported approach results in a simpler ionic composition than the more widely adopted synthesis route of combining PhMgCl with AlCl3. Electrochemical performance has been validated by polarisation tests and cyclic voltammetry, which demonstrate excellent stability of electrolytes produced via this atom-efficient approach.
Original languageEnglish
Pages (from-to)12070-12073
Number of pages4
JournalChemical Communications
Volume58
Issue number86
Early online date3 Oct 2022
DOIs
Publication statusPublished - 3 Oct 2022

Keywords

  • atom-efficient synthesis
  • benchmark electrolyte
  • magneisum battery applications
  • electrochemical performance
  • ligand exchange reaction
  • electrolyte stability

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