Aromatic peptide amphiphiles: significance of the Fmoc moiety

Scott Fleming; Sisir Debnath; Pim W J M Frederix; Tell Tuttle; Rein V Ulijn

doi:10.1039/c3cc45822a

Aromatic peptide amphiphiles: significance of the Fmoc moiety

Scott Fleming, Sisir Debnath, Pim W J M Frederix, Tell Tuttle, Rein V Ulijn

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123 Citations (Scopus)

Abstract

Aromatic peptide amphiphile hydrogelators commonly utilise the fluorenyl-9-methoxycarbonyl moiety as an N-terminal capping group. Material properties and spectroscopic techniques show the influence of alternative linkers between the fluorenyl moiety and the peptide. This study establishes whether methoxycarbonyl is an optimal or mainly convenient linker, for this class of self-assembling systems.

Original language	English
Pages (from-to)	10587-10589
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	90
DOIs	https://doi.org/10.1039/c3cc45822a
Publication status	Published - 21 Nov 2013

Keywords

amphiphile hydrogelator s
methoxycarbonyl

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10.1039/c3cc45822a

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abstract = "Aromatic peptide amphiphile hydrogelators commonly utilise the fluorenyl-9-methoxycarbonyl moiety as an N-terminal capping group. Material properties and spectroscopic techniques show the influence of alternative linkers between the fluorenyl moiety and the peptide. This study establishes whether methoxycarbonyl is an optimal or mainly convenient linker, for this class of self-assembling systems.",

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AU - Fleming, Scott

AU - Debnath, Sisir

AU - Frederix, Pim W J M

AU - Tuttle, Tell

AU - Ulijn, Rein V

PY - 2013/11/21

Y1 - 2013/11/21

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AB - Aromatic peptide amphiphile hydrogelators commonly utilise the fluorenyl-9-methoxycarbonyl moiety as an N-terminal capping group. Material properties and spectroscopic techniques show the influence of alternative linkers between the fluorenyl moiety and the peptide. This study establishes whether methoxycarbonyl is an optimal or mainly convenient linker, for this class of self-assembling systems.

KW - amphiphile hydrogelator s

KW - methoxycarbonyl

U2 - 10.1039/c3cc45822a

DO - 10.1039/c3cc45822a

M3 - Article

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SN - 1364-548X

VL - 49

SP - 10587

EP - 10589

JO - Chemical Communications

JF - Chemical Communications

IS - 90

ER -

Aromatic peptide amphiphiles: significance of the Fmoc moiety

Abstract

Keywords

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