Anomalous heat transport in binary hard-sphere gases

Craig Moir, Leo Lue, Julian D. Gale, Paolo Raiteri, Marcus N. Bannerman

Research output: Contribution to journalArticle

Abstract

Equilibrium and non-equilibrium molecular dynamics (MD) are used to investigate the thermal conductivity of binary hard-sphere fluids. It is found that the thermal conductivity of a mixture can not only lie outside the series and parallel bounds set by their pure component values, but can lie beyond even the pure component fluid values. The MD simulations verify that revised Enskog theory can accurately predict non-equilibrium thermal conductivities at low densities and this theory is applied to explore the model parameter space. Only certain mass and size ratios are found to exhibit conductivity enhancements above the parallel bounds and dehancement below the series bounds. The anomalous dehancement is experimentally accessible in helium-hydrogen gas mixtures and a review of the literature confirms the existance of mixture thermal conductivity below the series bound and even below the pure fluid values, in accordance with the predictions of revised Enskog theory. The results reported here may reignite the debate in the nanofluid literature on the possible existence of anomalous thermal conductivities outside the series/parallel bounds as this work demonstrates they are a fundamental feature of even simple fluids.
LanguageEnglish
Article number030102
Number of pages5
JournalPhysical Review E
Volume99
Issue number3
DOIs
Publication statusPublished - 29 Mar 2019

Fingerprint

Heat Transport
Hard Spheres
Thermal Conductivity
Anomalous
Thermal conductivity
thermal conductivity
Gases
Binary
heat
gases
Fluids
Series
fluids
Fluid
Molecular dynamics
molecular dynamics
Hard-sphere Fluid
Non-equilibrium Molecular Dynamics
Nanofluid
Helium

Keywords

  • molecular dynamics (MD)
  • thermal conductivity
  • Enskog theory
  • binary hard-sphere fluids

Cite this

Moir, C., Lue, L., Gale, J. D., Raiteri, P., & Bannerman, M. N. (2019). Anomalous heat transport in binary hard-sphere gases. Physical Review E, 99(3), [030102]. https://doi.org/10.1103/PhysRevE.99.030102
Moir, Craig ; Lue, Leo ; Gale, Julian D. ; Raiteri, Paolo ; Bannerman, Marcus N. / Anomalous heat transport in binary hard-sphere gases. In: Physical Review E. 2019 ; Vol. 99, No. 3.
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Moir, C, Lue, L, Gale, JD, Raiteri, P & Bannerman, MN 2019, 'Anomalous heat transport in binary hard-sphere gases' Physical Review E, vol. 99, no. 3, 030102. https://doi.org/10.1103/PhysRevE.99.030102

Anomalous heat transport in binary hard-sphere gases. / Moir, Craig; Lue, Leo; Gale, Julian D.; Raiteri, Paolo ; Bannerman, Marcus N.

In: Physical Review E, Vol. 99, No. 3, 030102, 29.03.2019.

Research output: Contribution to journalArticle

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