Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Synthesis of a series of iridium(I) complexes of the type [(COD)Ir(IMes)(PPh3)]X (X = BF4, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.
LanguageEnglish
Pages7927-7931
Number of pages5
JournalOrganic and Biomolecular Chemistry
Volume12
Issue number40
Early online date2 Sep 2014
DOIs
Publication statusPublished - Oct 2014

Fingerprint

Iridium
hydrogen isotopes
crack opening displacement
iridium
Catalysis
Isotopes
catalysis
Anions
Hydrogen
Ion exchange
anions
catalysts
Catalysts
synthesis

Keywords

  • hydrogen isotope exchange processes
  • solvent scope
  • iridium(I) complexes

Cite this

@article{b34572b7abe2419c8fe4b79cc0dd86a8,
title = "Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes",
abstract = "Synthesis of a series of iridium(I) complexes of the type [(COD)Ir(IMes)(PPh3)]X (X = BF4, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.",
keywords = "hydrogen isotope exchange processes, solvent scope, iridium(I) complexes",
author = "Kennedy, {Alan R} and William Kerr and Rory Moir and Marc Reid",
year = "2014",
month = "10",
doi = "10.1039/C4OB01570C",
language = "English",
volume = "12",
pages = "7927--7931",
journal = "Organic and Biomolecular Chemistry",
issn = "1477-0520",
number = "40",

}

Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes. / Kennedy, Alan R; Kerr, William; Moir, Rory; Reid, Marc.

In: Organic and Biomolecular Chemistry, Vol. 12, No. 40, 10.2014, p. 7927-7931.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

AU - Kennedy, Alan R

AU - Kerr, William

AU - Moir, Rory

AU - Reid, Marc

PY - 2014/10

Y1 - 2014/10

N2 - Synthesis of a series of iridium(I) complexes of the type [(COD)Ir(IMes)(PPh3)]X (X = BF4, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.

AB - Synthesis of a series of iridium(I) complexes of the type [(COD)Ir(IMes)(PPh3)]X (X = BF4, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.

KW - hydrogen isotope exchange processes

KW - solvent scope

KW - iridium(I) complexes

UR - http://pubs.rsc.org/en/journals/journalissues/ob

U2 - 10.1039/C4OB01570C

DO - 10.1039/C4OB01570C

M3 - Article

VL - 12

SP - 7927

EP - 7931

JO - Organic and Biomolecular Chemistry

T2 - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

SN - 1477-0520

IS - 40

ER -