Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

Alan R Kennedy; William Kerr; Rory Moir; Marc Reid

doi:10.1039/C4OB01570C

Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

Alan R Kennedy, William Kerr, Rory Moir, Marc Reid

Pure And Applied Chemistry

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Abstract

Synthesis of a series of iridium(I) complexes of the type [(COD)Ir(IMes)(PPh3)]X (X = BF4, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.

Original language	English
Pages (from-to)	7927-7931
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	12
Issue number	40
Early online date	2 Sept 2014
DOIs	https://doi.org/10.1039/C4OB01570C
Publication status	Published - Oct 2014

Keywords

hydrogen isotope exchange processes
solvent scope
iridium(I) complexes

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10.1039/C4OB01570C

Kennedy-etal-OBC2014-anion-effects-to-deliver-enhanced-iridium-catalystsAccepted author manuscript, 816 KB

Cite this

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title = "Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes",

abstract = "Synthesis of a series of iridium(I) complexes of the type [(COD)Ir(IMes)(PPh3)]X (X = BF4, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.",

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author = "Kennedy, {Alan R} and William Kerr and Rory Moir and Marc Reid",

year = "2014",

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language = "English",

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T1 - Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

AU - Kennedy, Alan R

AU - Kerr, William

AU - Moir, Rory

AU - Reid, Marc

PY - 2014/10

Y1 - 2014/10

N2 - Synthesis of a series of iridium(I) complexes of the type [(COD)Ir(IMes)(PPh3)]X (X = BF4, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.

AB - Synthesis of a series of iridium(I) complexes of the type [(COD)Ir(IMes)(PPh3)]X (X = BF4, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.

KW - hydrogen isotope exchange processes

KW - solvent scope

KW - iridium(I) complexes

UR - http://pubs.rsc.org/en/journals/journalissues/ob

U2 - 10.1039/C4OB01570C

DO - 10.1039/C4OB01570C

M3 - Article

SN - 1477-0520

VL - 12

SP - 7927

EP - 7931

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 40

ER -

Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

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Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

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