Synthesis of a series of iridium(I) complexes of the type [(COD)Ir(IMes)(PPh3)]X (X = BF4, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.
|Number of pages||5|
|Journal||Organic and Biomolecular Chemistry|
|Early online date||2 Sept 2014|
|Publication status||Published - Oct 2014|
- hydrogen isotope exchange processes
- solvent scope
- iridium(I) complexes