Analytical solution of the proper integral-equations for interaction site fluids

L. Lue, D. Blankschtein

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

We apply the Wiener-Hopf factorization technique to the Chandler-Silbey-Ladanyi equations with the Percus-Yevick closure for a general fluid composed of hard-sphere interaction sites. We analytically solve these equations for symmetric n- atomic tangent hard-sphere molecules (n less than or equal to 4), and obtain closed analytical expressions for the equation of stare and other thermodynamic properties of the fluid.
Original languageEnglish
Pages (from-to)1229-1231
Number of pages2
JournalJournal of Chemical Physics
Volume103
Issue number3
DOIs
Publication statusPublished - 15 Jul 1995

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Keywords

  • diatomics
  • integral equations
  • analytical solution
  • hard−sphere model
  • equations of state
  • thermodynamic properties
  • liquid structure

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