An intermediate temperature fuel cell based on composite electrolyte of carbonate and doped barium cerate with SrFe0.7Mn0.2Mo 0.1O3-δ cathode

Lei Zhang; Rong Lan; Shanwen Tao

doi:10.1016/j.ijhydene.2013.06.029

An intermediate temperature fuel cell based on composite electrolyte of carbonate and doped barium cerate with SrFe_0.7Mn_0.2Mo _0.1O_3-δ cathode

Lei Zhang, Rong Lan, Shanwen Tao

Research output: Contribution to journal › Article › peer-review

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Abstract

BaCeO₃-based proton conductor BaCe_0.5Zr _0.3Y_0.16Zn_0.04O_3-δ (BCZYZn) was adopted as a part of the oxide-carbonate composite electrolyte. The total ionic conductivity of BCZYZn-carbonate composite is 0.28 S cm^-1 at 500 C. Perovskite oxide SrFe_0.7Mn_0.2Mo_0.1O _3-δ was developed and used as cathode. It was found that SrFe_0.7Mn_0.2Mo_0.1O_3-δ exhibits a primitive cubic structure with space group Pm3m(221); a = 3.8790(1) Å, V = 58.364(1) Å³. The electrical conductivity of SrFe _0.7Mn_0.2Mo_0.1O_3-δ is 15-26 S cm^-1 in the temperature range 400-700 C measured by d.c. method. Single cell with BCZYZn-carbonate composite electrolyte and SrFe _0.7Mn_0.2Mo_0.1O_3-δ cathode was fabricated and tested with humidified H₂ (∼3 vol% H₂O) as fuel and air as oxidant. A similar configuration cell with lithiated NiO cathode was also constructed for comparison. It was found that neither BaCe _0.5Zr_0.3Y_0.16Zn_0.04O _3-δ nor SrFe_0.7Mn_0.2Mo _0.1O_3-δ is chemically compatible with (Li,Na) ₂CO₃. The fuel cell performance is not as good as those based on doped ceria-carbonate electrolytes.

Original language	English
Pages (from-to)	16546-16551
Number of pages	6
Journal	International Journal of Hydrogen Energy
Volume	38
Issue number	36
Early online date	12 Jul 2013
DOIs	https://doi.org/10.1016/j.ijhydene.2013.06.029
Publication status	Published - 13 Dec 2013

Keywords

cathode
conductivity
fuel cell
oxide-carbonate composite
perovskite

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.ijhydene.2013.06.029

Zhang-etal-IJHT2013-an-intermediate-temperature-fuel-cell-based-on-composite-electrolyteAccepted author manuscript, 572 KB

Cite this

@article{cadf7c65548a4f089e381997e2a049ac,

title = "An intermediate temperature fuel cell based on composite electrolyte of carbonate and doped barium cerate with SrFe0.7Mn0.2Mo 0.1O3-δ cathode",

abstract = "BaCeO3-based proton conductor BaCe0.5Zr 0.3Y0.16Zn0.04O3-δ (BCZYZn) was adopted as a part of the oxide-carbonate composite electrolyte. The total ionic conductivity of BCZYZn-carbonate composite is 0.28 S cm-1 at 500 C. Perovskite oxide SrFe0.7Mn0.2Mo0.1O 3-δ was developed and used as cathode. It was found that SrFe0.7Mn0.2Mo0.1O3-δ exhibits a primitive cubic structure with space group Pm3m(221); a = 3.8790(1) {\AA}, V = 58.364(1) {\AA}3. The electrical conductivity of SrFe 0.7Mn0.2Mo0.1O3-δ is 15-26 S cm-1 in the temperature range 400-700 C measured by d.c. method. Single cell with BCZYZn-carbonate composite electrolyte and SrFe 0.7Mn0.2Mo0.1O3-δ cathode was fabricated and tested with humidified H2 (∼3 vol% H2O) as fuel and air as oxidant. A similar configuration cell with lithiated NiO cathode was also constructed for comparison. It was found that neither BaCe 0.5Zr0.3Y0.16Zn0.04O 3-δ nor SrFe0.7Mn0.2Mo 0.1O3-δ is chemically compatible with (Li,Na) 2CO3. The fuel cell performance is not as good as those based on doped ceria-carbonate electrolytes.",

keywords = "cathode, conductivity, fuel cell, oxide-carbonate composite, perovskite",

author = "Lei Zhang and Rong Lan and Shanwen Tao",

note = "NOTICE: this is the author{\textquoteright}s version of a work that was accepted for publication in International Journal of Hydrogen Energy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in International Journal of Hydrogen Energy, VOL38, ISSUE36, (2013) DOI: 10.1016/j.ijhydene.2013.06.029",

year = "2013",

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day = "13",

doi = "10.1016/j.ijhydene.2013.06.029",

language = "English",

volume = "38",

pages = "16546--16551",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

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T1 - An intermediate temperature fuel cell based on composite electrolyte of carbonate and doped barium cerate with SrFe0.7Mn0.2Mo 0.1O3-δ cathode

AU - Zhang, Lei

AU - Lan, Rong

AU - Tao, Shanwen

N1 - NOTICE: this is the author’s version of a work that was accepted for publication in International Journal of Hydrogen Energy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in International Journal of Hydrogen Energy, VOL38, ISSUE36, (2013) DOI: 10.1016/j.ijhydene.2013.06.029

PY - 2013/12/13

Y1 - 2013/12/13

N2 - BaCeO3-based proton conductor BaCe0.5Zr 0.3Y0.16Zn0.04O3-δ (BCZYZn) was adopted as a part of the oxide-carbonate composite electrolyte. The total ionic conductivity of BCZYZn-carbonate composite is 0.28 S cm-1 at 500 C. Perovskite oxide SrFe0.7Mn0.2Mo0.1O 3-δ was developed and used as cathode. It was found that SrFe0.7Mn0.2Mo0.1O3-δ exhibits a primitive cubic structure with space group Pm3m(221); a = 3.8790(1) Å, V = 58.364(1) Å3. The electrical conductivity of SrFe 0.7Mn0.2Mo0.1O3-δ is 15-26 S cm-1 in the temperature range 400-700 C measured by d.c. method. Single cell with BCZYZn-carbonate composite electrolyte and SrFe 0.7Mn0.2Mo0.1O3-δ cathode was fabricated and tested with humidified H2 (∼3 vol% H2O) as fuel and air as oxidant. A similar configuration cell with lithiated NiO cathode was also constructed for comparison. It was found that neither BaCe 0.5Zr0.3Y0.16Zn0.04O 3-δ nor SrFe0.7Mn0.2Mo 0.1O3-δ is chemically compatible with (Li,Na) 2CO3. The fuel cell performance is not as good as those based on doped ceria-carbonate electrolytes.

AB - BaCeO3-based proton conductor BaCe0.5Zr 0.3Y0.16Zn0.04O3-δ (BCZYZn) was adopted as a part of the oxide-carbonate composite electrolyte. The total ionic conductivity of BCZYZn-carbonate composite is 0.28 S cm-1 at 500 C. Perovskite oxide SrFe0.7Mn0.2Mo0.1O 3-δ was developed and used as cathode. It was found that SrFe0.7Mn0.2Mo0.1O3-δ exhibits a primitive cubic structure with space group Pm3m(221); a = 3.8790(1) Å, V = 58.364(1) Å3. The electrical conductivity of SrFe 0.7Mn0.2Mo0.1O3-δ is 15-26 S cm-1 in the temperature range 400-700 C measured by d.c. method. Single cell with BCZYZn-carbonate composite electrolyte and SrFe 0.7Mn0.2Mo0.1O3-δ cathode was fabricated and tested with humidified H2 (∼3 vol% H2O) as fuel and air as oxidant. A similar configuration cell with lithiated NiO cathode was also constructed for comparison. It was found that neither BaCe 0.5Zr0.3Y0.16Zn0.04O 3-δ nor SrFe0.7Mn0.2Mo 0.1O3-δ is chemically compatible with (Li,Na) 2CO3. The fuel cell performance is not as good as those based on doped ceria-carbonate electrolytes.

KW - cathode

KW - conductivity

KW - fuel cell

KW - oxide-carbonate composite

KW - perovskite

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UR - http://www.sciencedirect.com/science/journal/aip/03603199

U2 - 10.1016/j.ijhydene.2013.06.029

DO - 10.1016/j.ijhydene.2013.06.029

M3 - Article

AN - SCOPUS:84888001072

VL - 38

SP - 16546

EP - 16551

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 36

ER -

An intermediate temperature fuel cell based on composite electrolyte of carbonate and doped barium cerate with SrFe_0.7Mn_0.2Mo _0.1O_3-δ cathode

Abstract

Keywords

UN SDGs

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Transfer From H-W: Shanwen Tao:Supergen: Fuel Cells Powering Greener Future (Phase 2),

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An intermediate temperature fuel cell based on composite electrolyte of carbonate and doped barium cerate with SrFe0.7Mn0.2Mo 0.1O3-δ cathode

Abstract

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Projects

Transfer From H-W: Shanwen Tao:Supergen: Fuel Cells Powering Greener Future (Phase 2),

Cite this

An intermediate temperature fuel cell based on composite electrolyte of carbonate and doped barium cerate with SrFe_0.7Mn_0.2Mo _0.1O_3-δ cathode