An experimental investigation into quantifying CO2 leakage in aqueous environments using chemical tracers

Matthew B. Myers, Jennifer J. Roberts, Cameron White, Linda Stalker

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Chemical tracers can be an effective means of detecting, attributing and quantifying any leaks to the surface from geological CO2 stores. CO2 release experiments have found it difficult to ascertain the fate, or quantify the volume of CO2 without the application of tracers. However, a significant proportion of global CO2 storage capacity is located offshore, and the marine environment poses constraints that could limit the success of using tracers. These constraints include uncertainties in the behaviour of tracers in marine sediments and the water column and sampling challenges. However, to date there have been few experimental investigations to address these uncertainties. Here, we used a benchtop experimental setup to explore how effectively methane, a common constituent of captured CO2 and of reservoir fluids, can aid the quantitation of CO2 leakage in aqueous environments. The experiment simulated gas leakage into sediments that mimic the seabed, and we measured the partitioning of co-released gases under different environmental conditions and injection rates. We find that the style of seepage and the fate of the CO2 are affected by the presence of a sand layer and the injection rate. We discuss the implications for leak monitoring approaches, including how tracers may be used to quantify the leak rates and fate of CO2 in aqueous environments. Our work contributes to ongoing efforts to develop robust offshore monitoring system that will assure operators, regulatory bodies and the public of CO2 storage integrity,
LanguageEnglish
Pages91-99
Number of pages9
JournalChemical Geology
Volume511
Early online date22 Feb 2019
DOIs
Publication statusPublished - 20 Apr 2019

Fingerprint

Leakage (fluid)
leakage
Sediments
Gases
tracer
Monitoring
Methane
Seepage
Sand
Experiments
Sampling
Fluids
Water
gas
monitoring system
marine sediment
seepage
marine environment
partitioning
experiment

Keywords

  • carbon capture and storage
  • monitoring
  • offshore
  • leak
  • quantitation
  • environmental impact

Cite this

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title = "An experimental investigation into quantifying CO2 leakage in aqueous environments using chemical tracers",
abstract = "Chemical tracers can be an effective means of detecting, attributing and quantifying any leaks to the surface from geological CO2 stores. CO2 release experiments have found it difficult to ascertain the fate, or quantify the volume of CO2 without the application of tracers. However, a significant proportion of global CO2 storage capacity is located offshore, and the marine environment poses constraints that could limit the success of using tracers. These constraints include uncertainties in the behaviour of tracers in marine sediments and the water column and sampling challenges. However, to date there have been few experimental investigations to address these uncertainties. Here, we used a benchtop experimental setup to explore how effectively methane, a common constituent of captured CO2 and of reservoir fluids, can aid the quantitation of CO2 leakage in aqueous environments. The experiment simulated gas leakage into sediments that mimic the seabed, and we measured the partitioning of co-released gases under different environmental conditions and injection rates. We find that the style of seepage and the fate of the CO2 are affected by the presence of a sand layer and the injection rate. We discuss the implications for leak monitoring approaches, including how tracers may be used to quantify the leak rates and fate of CO2 in aqueous environments. Our work contributes to ongoing efforts to develop robust offshore monitoring system that will assure operators, regulatory bodies and the public of CO2 storage integrity,",
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An experimental investigation into quantifying CO2 leakage in aqueous environments using chemical tracers. / Myers, Matthew B.; Roberts, Jennifer J.; White, Cameron; Stalker, Linda.

In: Chemical Geology, Vol. 511, 20.04.2019, p. 91-99.

Research output: Contribution to journalArticle

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