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Abstract
Sodium TMP-zincate, [(TMEDA)Na(TMP)(Bu-t)Zn(Bu-t)], can deproto-zincate N-Boc pyrrolidine at ambient temperature in hexane solution, whereas in toluene the captured alpha-carbanion of the heterocycle attacks the solvent setting off a cascade of reactions that ultimately produce a pyrrolidine-substituted enolate.
Original language | English |
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Pages (from-to) | 5265-5267 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 48 |
Issue number | 43 |
DOIs | |
Publication status | Published - 2012 |
Keywords
- zincation
- N-Boc pyrrolidine
- solvent dependency
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Projects
- 2 Finished