Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides

K.J. Drewette; K.W. Henderson; A.R. Kennedy; R.E. Mulvey; C.T. O'Hara; R.B. Rowlings

doi:10.1039/b202549c

Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides

K.J. Drewette, K.W. Henderson, A.R. Kennedy, R.E. Mulvey, C.T. O'Hara, R.B. Rowlings

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

A series of composite lithium- or sodium-magnesium-alkoxide-diisopropylamides of general formula [{MMg[N(Pr-i)(2)](2)OR}(2)] (where M = Li, R = Oct(n); M = Na, R = Bu-n or Oct(n)), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.

Original language	English
Pages (from-to)	1176-1177
Number of pages	1
Journal	Chemical Communications (London)
Volume	2002
Issue number	11
DOIs	https://doi.org/10.1039/b202549c
Publication status	Published - 3 May 2002

Keywords

alkoxide
multidisciplinary chemistry

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10.1039/b202549c

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abstract = "A series of composite lithium- or sodium-magnesium-alkoxide-diisopropylamides of general formula [{MMg[N(Pr-i)(2)](2)OR}(2)] (where M = Li, R = Oct(n); M = Na, R = Bu-n or Oct(n)), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.",

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AU - Drewette, K.J.

AU - Henderson, K.W.

AU - Kennedy, A.R.

AU - Mulvey, R.E.

AU - O'Hara, C.T.

AU - Rowlings, R.B.

PY - 2002/5/3

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AB - A series of composite lithium- or sodium-magnesium-alkoxide-diisopropylamides of general formula [{MMg[N(Pr-i)(2)](2)OR}(2)] (where M = Li, R = Oct(n); M = Na, R = Bu-n or Oct(n)), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.

KW - alkoxide

KW - multidisciplinary chemistry

UR - http://dx.doi.org/10.1039/b202549c

U2 - 10.1039/b202549c

DO - 10.1039/b202549c

M3 - Article

SN - 0009-241X

VL - 2002

SP - 1176

EP - 1177

JO - Chemical Communications (London)

JF - Chemical Communications (London)

IS - 11

ER -

Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides

Abstract

Keywords

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Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides

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