Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides

K.J. Drewette, K.W. Henderson, A.R. Kennedy, R.E. Mulvey, C.T. O'Hara, R.B. Rowlings

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Abstract

A series of composite lithium- or sodium-magnesium-alkoxide-diisopropylamides of general formula [{MMg[N(Pr-i)(2)](2)OR}(2)] (where M = Li, R = Oct(n); M = Na, R = Bu-n or Oct(n)), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.
Original languageEnglish
Pages (from-to)1176-1177
Number of pages1
JournalChemical Communications (London)
Volume2002
Issue number11
DOIs
Publication statusPublished - 3 May 2002

Keywords

  • alkoxide
  • multidisciplinary chemistry

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