Agro-waste generated Pd/CAP-ash catalyzed ligand-free approach for Suzuki–Miyaura coupling reaction

Rupesh C. Patil; Ashutosh A. Jagdale; Uttam P. Patil; Jeevan S. Ghodake; Sawanta S. Mali; Chang K. Hong; Suresh S. Patil

doi:10.1007/s10562-021-03597-6

Agro-waste generated Pd/CAP-ash catalyzed ligand-free approach for Suzuki–Miyaura coupling reaction

Rupesh C. Patil, Ashutosh A. Jagdale, Uttam P. Patil, Jeevan S. Ghodake, Sawanta S. Mali, Chang K. Hong, Suresh S. Patil^*

^*Corresponding author for this work

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Abstract: We converted agro-waste Custard Apple Peels (CAP) to ash via thermal treatment, on which Pd(OAc)2 was immobilized easily that produced a low-cost, highly efficient Pd/CAP-ash catalyst. The prepared catalyst was fully characterized by using FT-IR, SEM, EDX, XRF, DSC-TGA, BET, HR-TEM, and XPS techniques. The Pd/CAP-ash catalyst was conveniently applied for the Suzuki–Miyaura coupling reaction under external base free and ligand-free conditions in an aqueous-organic solvent to produce biphenyls in good to excellent yields. The main attraction of our protocol an application of palladium-supported agro-waste material which is easily recoverable and recyclable provides mono and bis-coupled derivatives in a short reaction time. Graphic Abstract: [Figure not available: see fulltext.].

Original language	English
Pages (from-to)	3617-3631
Number of pages	15
Journal	Catalysis Letters
Volume	151
Issue number	12
Early online date	25 Mar 2021
DOIs	https://doi.org/10.1007/s10562-021-03597-6
Publication status	Published - Dec 2021

Funding

One of the authors, Rupesh C. Patil is grateful to Chhatrapati Shahu Maharaj Research Training and Human Development Institute (SARTHI), Pune (Government of Maharashtra), India for the award of the CMSRF-2019 fellowship. [CIN-U74999PN2018NPL177394, dated 11th Sept. 2019]

Keywords

Agro-waste
Custard apple peels
Palladium
Suzuki–Miyaura coupling

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10.1007/s10562-021-03597-6

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@article{dcdf2ff27076495ead2fa0b57d3c6648,

title = "Agro-waste generated Pd/CAP-ash catalyzed ligand-free approach for Suzuki–Miyaura coupling reaction",

abstract = "Abstract: We converted agro-waste Custard Apple Peels (CAP) to ash via thermal treatment, on which Pd(OAc)2 was immobilized easily that produced a low-cost, highly efficient Pd/CAP-ash catalyst. The prepared catalyst was fully characterized by using FT-IR, SEM, EDX, XRF, DSC-TGA, BET, HR-TEM, and XPS techniques. The Pd/CAP-ash catalyst was conveniently applied for the Suzuki–Miyaura coupling reaction under external base free and ligand-free conditions in an aqueous-organic solvent to produce biphenyls in good to excellent yields. The main attraction of our protocol an application of palladium-supported agro-waste material which is easily recoverable and recyclable provides mono and bis-coupled derivatives in a short reaction time. Graphic Abstract: [Figure not available: see fulltext.].",

keywords = "Agro-waste, Custard apple peels, Palladium, Suzuki–Miyaura coupling",

author = "Patil, {Rupesh C.} and Jagdale, {Ashutosh A.} and Patil, {Uttam P.} and Ghodake, {Jeevan S.} and Mali, {Sawanta S.} and Hong, {Chang K.} and Patil, {Suresh S.}",

year = "2021",

month = dec,

doi = "10.1007/s10562-021-03597-6",

language = "English",

volume = "151",

pages = "3617--3631",

number = "12",

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TY - JOUR

T1 - Agro-waste generated Pd/CAP-ash catalyzed ligand-free approach for Suzuki–Miyaura coupling reaction

AU - Patil, Rupesh C.

AU - Jagdale, Ashutosh A.

AU - Patil, Uttam P.

AU - Ghodake, Jeevan S.

AU - Mali, Sawanta S.

AU - Hong, Chang K.

AU - Patil, Suresh S.

PY - 2021/12

Y1 - 2021/12

N2 - Abstract: We converted agro-waste Custard Apple Peels (CAP) to ash via thermal treatment, on which Pd(OAc)2 was immobilized easily that produced a low-cost, highly efficient Pd/CAP-ash catalyst. The prepared catalyst was fully characterized by using FT-IR, SEM, EDX, XRF, DSC-TGA, BET, HR-TEM, and XPS techniques. The Pd/CAP-ash catalyst was conveniently applied for the Suzuki–Miyaura coupling reaction under external base free and ligand-free conditions in an aqueous-organic solvent to produce biphenyls in good to excellent yields. The main attraction of our protocol an application of palladium-supported agro-waste material which is easily recoverable and recyclable provides mono and bis-coupled derivatives in a short reaction time. Graphic Abstract: [Figure not available: see fulltext.].

AB - Abstract: We converted agro-waste Custard Apple Peels (CAP) to ash via thermal treatment, on which Pd(OAc)2 was immobilized easily that produced a low-cost, highly efficient Pd/CAP-ash catalyst. The prepared catalyst was fully characterized by using FT-IR, SEM, EDX, XRF, DSC-TGA, BET, HR-TEM, and XPS techniques. The Pd/CAP-ash catalyst was conveniently applied for the Suzuki–Miyaura coupling reaction under external base free and ligand-free conditions in an aqueous-organic solvent to produce biphenyls in good to excellent yields. The main attraction of our protocol an application of palladium-supported agro-waste material which is easily recoverable and recyclable provides mono and bis-coupled derivatives in a short reaction time. Graphic Abstract: [Figure not available: see fulltext.].

KW - Agro-waste

KW - Custard apple peels

KW - Palladium

KW - Suzuki–Miyaura coupling

UR - http://www.scopus.com/inward/record.url?scp=85103300413&partnerID=8YFLogxK

U2 - 10.1007/s10562-021-03597-6

DO - 10.1007/s10562-021-03597-6

M3 - Article

AN - SCOPUS:85103300413

SN - 1011-372X

VL - 151

SP - 3617

EP - 3631

JO - Catalysis Letters

JF - Catalysis Letters

IS - 12

ER -

Agro-waste generated Pd/CAP-ash catalyzed ligand-free approach for Suzuki–Miyaura coupling reaction

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Keywords

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