### Abstract

The kinetics of reaction-limited cluster aggregation of fluorinated polymer colloids in a broad range of particle volume fractions has been investigated experimentally by measuring independently the Fuchs stability ratio W and the time evolution of both the average radius of gyration <R-g> and the average hydrodynamic radius <R-h> of the aggregates mass distribution. The W value is determined from the aggregation rate at the very initial stage of the aggregation, where the presence of triplets is negligible. The time evolutions of <R-g> and <R-h> are then simulated using the cluster mass distribution calculated from the population balance equations with various aggregation kernels proposed in the literature. It is found that, when the measured W value is used, the only kernels that can correctly simulate the experimental results are the product kernel and the one derived by Odriozola et al. (Europhys. Lett. 53 (2001) 797), with some proper tuning of the exponent in the kernel. For the particle volume fraction phi < 1%, the obtained value for the exponent is 0.4 and independent of phi, while it tends to decrease for larger 4 values, most likely indicating a significant effect of multi-body interactions on the aggregation kinetics.

Language | English |
---|---|

Pages | 33-56 |

Number of pages | 24 |

Journal | Advances in Colloid and Interface Science |

Volume | 103 |

Issue number | 1 |

DOIs | |

Publication status | Published - 19 Mar 2003 |

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### Keywords

- aggregation kinetics
- radius of gyration
- hydrodynamic radius
- stability ratio
- aggregation kernel

### Cite this

*Advances in Colloid and Interface Science*,

*103*(1), 33-56. https://doi.org/10.1016/S0001-8686(02)00082-9

}

*Advances in Colloid and Interface Science*, vol. 103, no. 1, pp. 33-56. https://doi.org/10.1016/S0001-8686(02)00082-9

**Aggregation kinetics of polymer colloids in reaction limited regime : experiments and simulations.** / Lattuada, M ; Sandkuhler, P ; Wu, H ; Sefcik, J ; Morbidelli, M .

Research output: Contribution to journal › Article

TY - JOUR

T1 - Aggregation kinetics of polymer colloids in reaction limited regime

T2 - Advances in Colloid and Interface Science

AU - Lattuada, M

AU - Sandkuhler, P

AU - Wu, H

AU - Sefcik, J

AU - Morbidelli, M

PY - 2003/3/19

Y1 - 2003/3/19

N2 - The kinetics of reaction-limited cluster aggregation of fluorinated polymer colloids in a broad range of particle volume fractions has been investigated experimentally by measuring independently the Fuchs stability ratio W and the time evolution of both the average radius of gyration <R-g> and the average hydrodynamic radius <R-h> of the aggregates mass distribution. The W value is determined from the aggregation rate at the very initial stage of the aggregation, where the presence of triplets is negligible. The time evolutions of <R-g> and <R-h> are then simulated using the cluster mass distribution calculated from the population balance equations with various aggregation kernels proposed in the literature. It is found that, when the measured W value is used, the only kernels that can correctly simulate the experimental results are the product kernel and the one derived by Odriozola et al. (Europhys. Lett. 53 (2001) 797), with some proper tuning of the exponent in the kernel. For the particle volume fraction phi < 1%, the obtained value for the exponent is 0.4 and independent of phi, while it tends to decrease for larger 4 values, most likely indicating a significant effect of multi-body interactions on the aggregation kinetics.

AB - The kinetics of reaction-limited cluster aggregation of fluorinated polymer colloids in a broad range of particle volume fractions has been investigated experimentally by measuring independently the Fuchs stability ratio W and the time evolution of both the average radius of gyration <R-g> and the average hydrodynamic radius <R-h> of the aggregates mass distribution. The W value is determined from the aggregation rate at the very initial stage of the aggregation, where the presence of triplets is negligible. The time evolutions of <R-g> and <R-h> are then simulated using the cluster mass distribution calculated from the population balance equations with various aggregation kernels proposed in the literature. It is found that, when the measured W value is used, the only kernels that can correctly simulate the experimental results are the product kernel and the one derived by Odriozola et al. (Europhys. Lett. 53 (2001) 797), with some proper tuning of the exponent in the kernel. For the particle volume fraction phi < 1%, the obtained value for the exponent is 0.4 and independent of phi, while it tends to decrease for larger 4 values, most likely indicating a significant effect of multi-body interactions on the aggregation kinetics.

KW - aggregation kinetics

KW - radius of gyration

KW - hydrodynamic radius

KW - stability ratio

KW - aggregation kernel

U2 - 10.1016/S0001-8686(02)00082-9

DO - 10.1016/S0001-8686(02)00082-9

M3 - Article

VL - 103

SP - 33

EP - 56

JO - Advances in Colloid and Interface Science

JF - Advances in Colloid and Interface Science

SN - 0001-8686

IS - 1

ER -