Advances in the cobalt-catalysed Pauson-Khand reaction: development of a sulfide-promoted, microwave-assisted protocol

Alison R. Cochrane; William J. Kerr; Laura C. Paterson; Colin M. Pearson; Paul Shaw

Advances in the cobalt-catalysed Pauson-Khand reaction: development of a sulfide-promoted, microwave-assisted protocol

Alison R. Cochrane, William J. Kerr, Laura C. Paterson, Colin M. Pearson, Paul Shaw

Pure And Applied Chemistry

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Abstract

The development of a sulfide-promoted, microwave-assisted Pauson-Khand reaction has enabled the formation of fused cyclopentenones using sub-stoichiometric quantities of a cobalt mediator over rapid reaction times and with no requirement for an external source of toxic carbon monoxide gas. This protocol displays applicability to both intra- and intermolecular Pauson-Khand reaction examples.

Original language	English
Journal	Tetrahedron
Publication status	Accepted/In press - 19 Nov 2020

Keywords

catalysis
cobalt
Pauson-Khand

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Cochrane-etal-Tetrahedron-2020-Advances-in-the-cobalt-catalysed-Pauson-Khand-reactionAccepted author manuscript, 881 KBLicence: CC BY-NC-ND 4.0

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title = "Advances in the cobalt-catalysed Pauson-Khand reaction: development of a sulfide-promoted, microwave-assisted protocol",

abstract = "The development of a sulfide-promoted, microwave-assisted Pauson-Khand reaction has enabled the formation of fused cyclopentenones using sub-stoichiometric quantities of a cobalt mediator over rapid reaction times and with no requirement for an external source of toxic carbon monoxide gas. This protocol displays applicability to both intra- and intermolecular Pauson-Khand reaction examples.",

keywords = "catalysis, cobalt, Pauson-Khand",

author = "Cochrane, {Alison R.} and Kerr, {William J.} and Paterson, {Laura C.} and Pearson, {Colin M.} and Paul Shaw",

year = "2020",

month = nov,

day = "19",

language = "English",

journal = "Tetrahedron",

issn = "0040-4020",

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T1 - Advances in the cobalt-catalysed Pauson-Khand reaction

T2 - development of a sulfide-promoted, microwave-assisted protocol

AU - Cochrane, Alison R.

AU - Kerr, William J.

AU - Paterson, Laura C.

AU - Pearson, Colin M.

AU - Shaw, Paul

PY - 2020/11/19

Y1 - 2020/11/19

N2 - The development of a sulfide-promoted, microwave-assisted Pauson-Khand reaction has enabled the formation of fused cyclopentenones using sub-stoichiometric quantities of a cobalt mediator over rapid reaction times and with no requirement for an external source of toxic carbon monoxide gas. This protocol displays applicability to both intra- and intermolecular Pauson-Khand reaction examples.

AB - The development of a sulfide-promoted, microwave-assisted Pauson-Khand reaction has enabled the formation of fused cyclopentenones using sub-stoichiometric quantities of a cobalt mediator over rapid reaction times and with no requirement for an external source of toxic carbon monoxide gas. This protocol displays applicability to both intra- and intermolecular Pauson-Khand reaction examples.

KW - catalysis

KW - cobalt

KW - Pauson-Khand

UR - https://www.sciencedirect.com/journal/tetrahedron

M3 - Article

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

ER -

Advances in the cobalt-catalysed Pauson-Khand reaction: development of a sulfide-promoted, microwave-assisted protocol

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