Abstract
Adsorption dynamics are of fundamental importance in applications of adsorbents in real situations. The adsorption/desorption characteristics of a series of adsorbates, with varying hydrophilic/hydrophobic and structural characteristics, for activated carbon BAX950, were investigated for temperatures in the range 288-323 K. These data provide a comprehensive kinetic study of adsorption/desorption for an activated carbon. The results are discussed in relation to the adsorbent pore structure and functional group concentration, adsorptive structure and adsorption mechanism. The study provides evidence for a compensation effect where activation energy and ln(pre-exponential factor) parameters obtained from the Arrhenius equation exhibit a linear correlation.
Original language | English |
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Pages (from-to) | 989-1004 |
Number of pages | 15 |
Journal | Carbon |
Volume | 44 |
Issue number | 5 |
DOIs | |
Publication status | Published - Apr 2006 |
Keywords
- activated carbon
- adsorption
- activation energy
- diffusion
- porosity