Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

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Abstract

New coordination complexes of the neutral tripodal tetraamine Me6TREN with tBu(3)Ga or tBu(2)Zn have been synthesised and studied with their molecular structures revealing, for the first time, coordination to metal centres via an eta(1) or eta(2) mode, adding to previously reported eta(3) and eta(4) ligated examples.

Original languageEnglish
Pages (from-to)10141-10144
Number of pages4
JournalDalton Transactions
Volume41
Issue number34
Early online date22 Jun 2012
DOIs
Publication statusPublished - 2012

Keywords

  • low denticity
  • coordination modes
  • high denticity
  • tripodal ligand
  • coordinative repertoire

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