Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

Thomas Cadenbach; Eva Hevia; Alan Kennedy; Robert E. Mulvey; Janie-Anne Pickrell; Stuart D. Robertson

doi:10.1039/c2dt31061a

Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

Thomas Cadenbach, Eva Hevia, Alan Kennedy, Robert E. Mulvey, Janie-Anne Pickrell, Stuart D. Robertson

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

New coordination complexes of the neutral tripodal tetraamine Me6TREN with tBu(3)Ga or tBu(2)Zn have been synthesised and studied with their molecular structures revealing, for the first time, coordination to metal centres via an eta(1) or eta(2) mode, adding to previously reported eta(3) and eta(4) ligated examples.

Original language	English
Pages (from-to)	10141-10144
Number of pages	4
Journal	Dalton Transactions
Volume	41
Issue number	34
Early online date	22 Jun 2012
DOIs	https://doi.org/10.1039/c2dt31061a
Publication status	Published - 2012

Keywords

low denticity
coordination modes
high denticity
tripodal ligand
coordinative repertoire

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10.1039/c2dt31061a

Cite this

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abstract = "New coordination complexes of the neutral tripodal tetraamine Me6TREN with tBu(3)Ga or tBu(2)Zn have been synthesised and studied with their molecular structures revealing, for the first time, coordination to metal centres via an eta(1) or eta(2) mode, adding to previously reported eta(3) and eta(4) ligated examples.",

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AU - Cadenbach, Thomas

AU - Hevia, Eva

AU - Kennedy, Alan

AU - Mulvey, Robert E.

AU - Pickrell, Janie-Anne

AU - Robertson, Stuart D.

PY - 2012

Y1 - 2012

N2 - New coordination complexes of the neutral tripodal tetraamine Me6TREN with tBu(3)Ga or tBu(2)Zn have been synthesised and studied with their molecular structures revealing, for the first time, coordination to metal centres via an eta(1) or eta(2) mode, adding to previously reported eta(3) and eta(4) ligated examples.

AB - New coordination complexes of the neutral tripodal tetraamine Me6TREN with tBu(3)Ga or tBu(2)Zn have been synthesised and studied with their molecular structures revealing, for the first time, coordination to metal centres via an eta(1) or eta(2) mode, adding to previously reported eta(3) and eta(4) ligated examples.

KW - low denticity

KW - coordination modes

KW - high denticity

KW - tripodal ligand

KW - coordinative repertoire

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UR - http://www.rsc.org/dalton

U2 - 10.1039/c2dt31061a

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ER -

Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

Abstract

Keywords

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EXPLOITING SYNTHETIC AND STRUCTURAL SYNERGISM IN ALKALI-METAL-MEDIATED ORGANOTRANSITIONMETALLATION (AMMO)

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Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

Abstract

Keywords

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EXPLOITING SYNTHETIC AND STRUCTURAL SYNERGISM IN ALKALI-METAL-MEDIATED ORGANOTRANSITIONMETALLATION (AMMO)

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