A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring

María José Heras Ojea; Giulia Lorusso; Gavin A. Craig; Claire Wilson; Marco Evangelisti; Mark Murrie

doi:10.1039/C7CC02243C

A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring

María José Heras Ojea, Giulia Lorusso, Gavin A. Craig, Claire Wilson, Marco Evangelisti, Mark Murrie

Pure And Applied Chemistry

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Abstract

The adiabatic temperature change of the star-shaped {CoIII3GdIII3} magnetocaloric ring is enhanced via topological control over the assembly process, by using a pre-formed {CoII(H6L)} building block that undergoes oxidation to CoIII, successfully separating the GdIII ions.

Original language	English
Pages (from-to)	4799-4802
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	35
Early online date	13 Apr 2017
DOIs	https://doi.org/10.1039/C7CC02243C
Publication status	Published - 1 May 2017

Keywords

adiabatic temperature change
magnetocaloric ring

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10.1039/C7CC02243CLicence: CC BY 3.0

Ojea-etal-CC-2017-A-topologically-unique-alternatingFinal published version, 2.03 MBLicence: CC BY 3.0

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title = "A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring",

abstract = "The adiabatic temperature change of the star-shaped {CoIII3GdIII3} magnetocaloric ring is enhanced via topological control over the assembly process, by using a pre-formed {CoII(H6L)} building block that undergoes oxidation to CoIII, successfully separating the GdIII ions.",

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T1 - A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring

AU - Ojea, María José Heras

AU - Lorusso, Giulia

AU - Craig, Gavin A.

AU - Wilson, Claire

AU - Evangelisti, Marco

AU - Murrie, Mark

PY - 2017/5/1

Y1 - 2017/5/1

N2 - The adiabatic temperature change of the star-shaped {CoIII3GdIII3} magnetocaloric ring is enhanced via topological control over the assembly process, by using a pre-formed {CoII(H6L)} building block that undergoes oxidation to CoIII, successfully separating the GdIII ions.

AB - The adiabatic temperature change of the star-shaped {CoIII3GdIII3} magnetocaloric ring is enhanced via topological control over the assembly process, by using a pre-formed {CoII(H6L)} building block that undergoes oxidation to CoIII, successfully separating the GdIII ions.

KW - adiabatic temperature change

KW - magnetocaloric ring

U2 - 10.1039/C7CC02243C

DO - 10.1039/C7CC02243C

M3 - Article

VL - 53

SP - 4799

EP - 4802

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 35

ER -

A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring

Abstract

Keywords

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