A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring

María José Heras Ojea, Giulia Lorusso, Gavin A. Craig, Claire Wilson, Marco Evangelisti, Mark Murrie

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Abstract

The adiabatic temperature change of the star-shaped {CoIII3GdIII3} magnetocaloric ring is enhanced via topological control over the assembly process, by using a pre-formed {CoII(H6L)} building block that undergoes oxidation to CoIII, successfully separating the GdIII ions.
Original languageEnglish
Pages (from-to)4799-4802
Number of pages4
JournalChemical Communications
Volume53
Issue number35
Early online date13 Apr 2017
DOIs
Publication statusPublished - 1 May 2017

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Keywords

  • adiabatic temperature change
  • magnetocaloric ring

Cite this

Ojea, M. J. H., Lorusso, G., Craig, G. A., Wilson, C., Evangelisti, M., & Murrie, M. (2017). A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring. Chemical Communications, 53(35), 4799-4802. https://doi.org/10.1039/C7CC02243C