A practical procedure for carbonyl α-oxidation: synthesis of (2-benzoyloxy)-1,4-cyclohexanedione mono-ethylene ketal

Teyrnon C. Jones; Nicholas C. O. Tomkinson

A practical procedure for carbonyl α-oxidation: synthesis of (2-benzoyloxy)-1,4-cyclohexanedione mono-ethylene ketal

Teyrnon C. Jones
, Nicholas C. O. Tomkinson

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A convenient method for the prepn. of α-acyloxy ketones is described. Oxyacylation of a variety of ketones with O-acyl hydroxyamine derivs. provided the corresponding α-acyloxy ketones in good yields. (2-Benzoyloxy)-1,4-cyclohexanedione mono-ethylene ketal was successfully synthesized from 1,4-cyclohexanedione mono-ethylene ketal.

Original language	Undefined/Unknown
Pages (from-to)	233-241
Number of pages	9
Journal	Organic Syntheses
Volume	84
Publication status	Published - 2007

Keywords

oxyacylation
ketones
α-acyloxy ketones
2-benzoyloxy

Cite this

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title = "A practical procedure for carbonyl α-oxidation: synthesis of (2-benzoyloxy)-1,4-cyclohexanedione mono-ethylene ketal",

abstract = "A convenient method for the prepn. of α-acyloxy ketones is described. Oxyacylation of a variety of ketones with O-acyl hydroxyamine derivs. provided the corresponding α-acyloxy ketones in good yields. (2-Benzoyloxy)-1,4-cyclohexanedione mono-ethylene ketal was successfully synthesized from 1,4-cyclohexanedione mono-ethylene ketal. ",

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author = "Jones, \{Teyrnon C.\} and Tomkinson, \{Nicholas C. O.\}",

year = "2007",

language = "Undefined/Unknown",

volume = "84",

pages = "233--241",

journal = "Organic Syntheses",

issn = "0078-6209",

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T1 - A practical procedure for carbonyl α-oxidation: synthesis of (2-benzoyloxy)-1,4-cyclohexanedione mono-ethylene ketal

AU - Jones, Teyrnon C.

AU - Tomkinson, Nicholas C. O.

PY - 2007

Y1 - 2007

N2 - A convenient method for the prepn. of α-acyloxy ketones is described. Oxyacylation of a variety of ketones with O-acyl hydroxyamine derivs. provided the corresponding α-acyloxy ketones in good yields. (2-Benzoyloxy)-1,4-cyclohexanedione mono-ethylene ketal was successfully synthesized from 1,4-cyclohexanedione mono-ethylene ketal.

AB - A convenient method for the prepn. of α-acyloxy ketones is described. Oxyacylation of a variety of ketones with O-acyl hydroxyamine derivs. provided the corresponding α-acyloxy ketones in good yields. (2-Benzoyloxy)-1,4-cyclohexanedione mono-ethylene ketal was successfully synthesized from 1,4-cyclohexanedione mono-ethylene ketal.

KW - oxyacylation

KW - ketones

KW - α-acyloxy ketones

KW - 2-benzoyloxy

UR - http://www.orgsyn.org/orgsyn/prep.asp?prep=v84p0233

M3 - Article

SN - 0078-6209

VL - 84

SP - 233

EP - 241

JO - Organic Syntheses

JF - Organic Syntheses

ER -

A practical procedure for carbonyl α-oxidation: synthesis of (2-benzoyloxy)-1,4-cyclohexanedione mono-ethylene ketal

Abstract

Keywords

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