A practical procedure for carbonyl α-oxidation: synthesis of (2-benzoyloxy)-1,4-cyclohexanedione mono-ethylene ketal

Teyrnon C. Jones, Nicholas C. O. Tomkinson

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A convenient method for the prepn. of α-acyloxy ketones is described. Oxyacylation of a variety of ketones with O-acyl hydroxyamine derivs. provided the corresponding α-acyloxy ketones in good yields. (2-Benzoyloxy)-1,4-cyclohexanedione mono-ethylene ketal was successfully synthesized from 1,4-cyclohexanedione mono-ethylene ketal.
Original languageUndefined/Unknown
Pages (from-to)233-241
Number of pages9
JournalOrganic Syntheses
Volume84
Publication statusPublished - 2007

Keywords

  • oxyacylation
  • ketones
  • α-acyloxy ketones
  • 2-benzoyloxy

Cite this