A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement

T. Khan; P.J. Skabara; S.J. Coles; M.B. Hursthouse

doi:10.1039/b009550h

A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement

T. Khan, P.J. Skabara, S.J. Coles, M.B. Hursthouse

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.

Original language	English
Pages (from-to)	369-370
Number of pages	1
Journal	Chemical Communications (London)
Volume	2001
Issue number	4
DOIs	https://doi.org/10.1039/b009550h
Publication status	Published - 2001

Keywords

chemistry
perchloric acid
thiones

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10.1039/b009550h

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title = "A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement",

abstract = "In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.",

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T1 - A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement

AU - Khan, T.

AU - Skabara, P.J.

AU - Coles, S.J.

AU - Hursthouse, M.B.

PY - 2001

Y1 - 2001

N2 - In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.

AB - In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.

KW - chemistry

KW - perchloric acid

KW - thiones

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UR - http://dx.doi.org/10.1039/b009550h

U2 - 10.1039/b009550h

DO - 10.1039/b009550h

M3 - Article

SN - 0009-241X

VL - 2001

SP - 369

EP - 370

JO - Chemical Communications (London)

JF - Chemical Communications (London)

IS - 4

ER -

A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement

Abstract

Keywords

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