A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement

T. Khan, P.J. Skabara, S.J. Coles, M.B. Hursthouse

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.
LanguageEnglish
Pages369-370
Number of pages1
JournalChemical Communications (London)
Volume2001
Issue number4
DOIs
Publication statusPublished - 2001

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Thiones
Crystal structure
X rays
Electrons
Perchloric Acid

Keywords

  • chemistry
  • perchloric acid
  • thiones

Cite this

Khan, T. ; Skabara, P.J. ; Coles, S.J. ; Hursthouse, M.B. / A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement. In: Chemical Communications (London). 2001 ; Vol. 2001, No. 4. pp. 369-370.
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A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement. / Khan, T.; Skabara, P.J.; Coles, S.J.; Hursthouse, M.B.

In: Chemical Communications (London), Vol. 2001, No. 4, 2001, p. 369-370.

Research output: Contribution to journalArticle

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AU - Khan, T.

AU - Skabara, P.J.

AU - Coles, S.J.

AU - Hursthouse, M.B.

PY - 2001

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AB - In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.

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KW - thiones

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JF - Chemical Communications (London)

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