A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement

T. Khan, P.J. Skabara, S.J. Coles, M.B. Hursthouse

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.
Original languageEnglish
Pages (from-to)369-370
Number of pages1
JournalChemical Communications (London)
Volume2001
Issue number4
DOIs
Publication statusPublished - 2001

Keywords

  • chemistry
  • perchloric acid
  • thiones

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