A novel neutral organic electron donor with record half-wave potential

Hardeep S Farwaha; Gotz Bucher; John A Murphy

doi:10.1039/C3OB41701H

A novel neutral organic electron donor with record half-wave potential

Hardeep S Farwaha, Gotz Bucher, John A Murphy

Pure And Applied Chemistry

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36 Citations (Scopus)

147 Downloads (Pure)

Abstract

Tricyclic donor 26 has been prepared and is the most reducing neutral ground-state organic molecule known, with an oxidation potential 260 mV more negative than the previous record. Cyclic voltammetry shows that a 2-electron reversible redox process occurs in DMF as solvent at −1.46 V vs. Ag/AgCl.

Original language	English
Pages (from-to)	8073-8081
Number of pages	9
Journal	Organic and Biomolecular Chemistry
Volume	11
DOIs	https://doi.org/10.1039/C3OB41701H
Publication status	Published - 6 Nov 2013

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10.1039/C3OB41701H

Farwaha-etal-OBC2013-novel-neutral-organic-electron-donorAccepted author manuscript, 1.03 MB

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title = "A novel neutral organic electron donor with record half-wave potential",

abstract = "Tricyclic donor 26 has been prepared and is the most reducing neutral ground-state organic molecule known, with an oxidation potential 260 mV more negative than the previous record. Cyclic voltammetry shows that a 2-electron reversible redox process occurs in DMF as solvent at −1.46 V vs. Ag/AgCl.",

author = "Farwaha, {Hardeep S} and Gotz Bucher and Murphy, {John A}",

year = "2013",

month = nov,

day = "6",

doi = "10.1039/C3OB41701H",

language = "English",

volume = "11",

pages = "8073--8081",

journal = "Organic and Biomolecular Chemistry",

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publisher = "Royal Society of Chemistry",

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T1 - A novel neutral organic electron donor with record half-wave potential

AU - Farwaha, Hardeep S

AU - Bucher, Gotz

AU - Murphy, John A

PY - 2013/11/6

Y1 - 2013/11/6

N2 - Tricyclic donor 26 has been prepared and is the most reducing neutral ground-state organic molecule known, with an oxidation potential 260 mV more negative than the previous record. Cyclic voltammetry shows that a 2-electron reversible redox process occurs in DMF as solvent at −1.46 V vs. Ag/AgCl.

AB - Tricyclic donor 26 has been prepared and is the most reducing neutral ground-state organic molecule known, with an oxidation potential 260 mV more negative than the previous record. Cyclic voltammetry shows that a 2-electron reversible redox process occurs in DMF as solvent at −1.46 V vs. Ag/AgCl.

UR - http://pubs.rsc.org/en/journals/journalissues/ob

U2 - 10.1039/C3OB41701H

DO - 10.1039/C3OB41701H

M3 - Article

SN - 1477-0520

VL - 11

SP - 8073

EP - 8081

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

ER -

A novel neutral organic electron donor with record half-wave potential

Abstract

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Light-Activated Approaches to Highly Challenging Organic Electron Transfer Reactions

Pathways to Impact Award

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A novel neutral organic electron donor with record half-wave potential

Abstract

Access to Document

Other files and links

Fingerprint

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Light-Activated Approaches to Highly Challenging Organic Electron Transfer Reactions

Pathways to Impact Award

Cite this