Projects per year
Tricyclic donor 26 has been prepared and is the most reducing neutral ground-state organic molecule known, with an oxidation potential 260 mV more negative than the previous record. Cyclic voltammetry shows that a 2-electron reversible redox process occurs in DMF as solvent at −1.46 V vs. Ag/AgCl.
Murphy, J. & Zhou, S.
1/07/13 → 30/06/15
Farwaha, H. S., Bucher, G., & Murphy, J. A. (2013). A novel neutral organic electron donor with record half-wave potential. Organic and Biomolecular Chemistry, 11, 8073-8081. https://doi.org/10.1039/C3OB41701H