Abstract
α,β-Unsatd. carbonyl compds. were cyclized with sulfonium ylides, the carbonyl compds. so formed were converted to alcs. by either using LiAlH4 or Grignard reagents. The alcs. were oxidized to β,γ-unsatd. carbonyl compds. using pyridinium chlorochromate (PCC), dichloromethane and water. Thus prepd. were 46-57% BzCH2CH:C(R)Ph (R = H, Ph, CH2Ph, p-tolyl).
| Original language | English |
|---|---|
| Pages (from-to) | 159-172 |
| Number of pages | 14 |
| Journal | Journal of the Iraqi Chemical Society |
| Volume | 13 |
| Issue number | 1 |
| Publication status | Published - 1988 |
Keywords
- carbonyl compounds
- sulfonium ylides
Cite this
Khalaf, A., Mustaffa, M. S., Ali, JA. H., Al-Dulaymi, J. R., & Hashem, A. K. (1988). A novel method for the preparation of β,γ-unsaturated carbonyl compounds. Journal of the Iraqi Chemical Society, 13(1), 159-172.