A new architecture in lithium amide chemistry: Synthesis of [{(c-C5H9)N(H)}(12)(O)Li-14], a cage molecule containing a salt-like, distorted, face-centred cube of lithium cations

W. Clegg; L. Horsburgh; P.R. Dennison; F.M. Mckenzie; Robert Mulvey

doi:10.1039/CC9960001065

A new architecture in lithium amide chemistry: Synthesis of [{(c-C5H9)N(H)}(12)(O)Li-14], a cage molecule containing a salt-like, distorted, face-centred cube of lithium cations

W. Clegg, L. Horsburgh, P.R. Dennison, F.M. Mckenzie, Robert Mulvey

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Synthesised in the presence of trace quantities of water, which can account for its central oxo anion, the tetradecalithium title compound represents a rare three-dimensional, high-oligomeric cage arrangement in an area generally populated by pseudo-two-dimensional ring and ladder structures.

Original language	English
Pages (from-to)	1065-1066
Number of pages	2
Journal	Chemical Communications
Volume	1996
Issue number	9
DOIs	https://doi.org/10.1039/CC9960001065
Publication status	Published - 7 May 1996

Keywords

ring structures
ladder structures
lithium amide

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10.1039/CC9960001065

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abstract = "Synthesised in the presence of trace quantities of water, which can account for its central oxo anion, the tetradecalithium title compound represents a rare three-dimensional, high-oligomeric cage arrangement in an area generally populated by pseudo-two-dimensional ring and ladder structures.",

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T2 - Synthesis of [{(c-C5H9)N(H)}(12)(O)Li-14], a cage molecule containing a salt-like, distorted, face-centred cube of lithium cations

AU - Clegg, W.

AU - Horsburgh, L.

AU - Dennison, P.R.

AU - Mckenzie, F.M.

AU - Mulvey, Robert

PY - 1996/5/7

Y1 - 1996/5/7

N2 - Synthesised in the presence of trace quantities of water, which can account for its central oxo anion, the tetradecalithium title compound represents a rare three-dimensional, high-oligomeric cage arrangement in an area generally populated by pseudo-two-dimensional ring and ladder structures.

AB - Synthesised in the presence of trace quantities of water, which can account for its central oxo anion, the tetradecalithium title compound represents a rare three-dimensional, high-oligomeric cage arrangement in an area generally populated by pseudo-two-dimensional ring and ladder structures.

KW - ring structures

KW - ladder structures

KW - lithium amide

U2 - 10.1039/CC9960001065

DO - 10.1039/CC9960001065

M3 - Article

SN - 1359-7345

VL - 1996

SP - 1065

EP - 1066

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

A new architecture in lithium amide chemistry: Synthesis of [{(c-C5H9)N(H)}(12)(O)Li-14], a cage molecule containing a salt-like, distorted, face-centred cube of lithium cations

Abstract

Keywords

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