Abstract
The structure of 1,3-bis(2,4,6-trimethylphenyl)-imidazol-2-ylidene-silver(I) chloride, 1, has been determined to be a monomer with weak head-to-tail H...Cl interactions in the solid state. A multinuclear NMR study using a C-13(carbene) labeled derivative, 1(C-13), exhibits C-13-Ag-107,Ag-109 coupling in solution. Further, the solid state CP/MAS NMR parameters, including the principal components of the chemical shift tensors for both the C-13 and Ag-109 centers, have been determined. With the aid of DFT calculations, the orientation of the chemical shift tensors have been assigned.
| Original language | English |
|---|---|
| Pages (from-to) | 1391-1393 |
| Number of pages | 2 |
| Journal | Inorganic Chemistry |
| Volume | 42 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 10 Mar 2003 |
Keywords
- HETEROCYCLIC CARBENE COMPLEXES
- COPPER(I) COMPLEXES
- SILVER
- SPECTROSCOPY
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Ramnial, T., Abernethy, C. D., Spicer, M. D., McKenzie, I. D., Gay, I. D., & Clyburne, J. A. C. (2003). A monomeric imidazol-2-ylidene-silver(I) chloride complex: Synthesis, structure, and solid state Ag-109 and C-13 CP/MAS NMR characterization. Inorganic Chemistry, 42(5), 1391-1393. https://doi.org/10.1021/ic0262381