A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets

José Sánchez Costa; Leoní A. Barrios; Gavin A. Craig; Simon J. Teat; Fernando Luis; Olivier Roubeau; Marco Evangelisti; Agustín Camón; Guillem Aromí

doi:10.1039/C1CC15682A

A molecular [Mn₁₄] coordination cluster featuring two slowly relaxing nanomagnets

José Sánchez Costa, Leoní A. Barrios, Gavin A. Craig, Simon J. Teat, Fernando Luis, Olivier Roubeau, Marco Evangelisti, Agustín Camón, Guillem Aromí

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

An extended polypyrazolyl ligand has been used to assemble Mn ions into high spin entities, in the form of one stable molecule composed of two well defined clusters. The slow relaxation of the magnetisation observed is demonstrated to arise from each “half-SMM” composing this molecular cluster pair.

Original language	English
Pages (from-to)	1413-1415
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	10
Early online date	18 Nov 2011
DOIs	https://doi.org/10.1039/C1CC15682A
Publication status	Published - 1 Feb 2012

Keywords

ligand
magnetisation
molecular cluster pair

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10.1039/C1CC15682A

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title = "A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets",

abstract = "An extended polypyrazolyl ligand has been used to assemble Mn ions into high spin entities, in the form of one stable molecule composed of two well defined clusters. The slow relaxation of the magnetisation observed is demonstrated to arise from each “half-SMM” composing this molecular cluster pair.",

keywords = "ligand, magnetisation, molecular cluster pair",

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AU - Costa, José Sánchez

AU - Barrios, Leoní A.

AU - Craig, Gavin A.

AU - Teat, Simon J.

AU - Luis, Fernando

AU - Roubeau, Olivier

AU - Evangelisti, Marco

AU - Camón, Agustín

AU - Aromí, Guillem

PY - 2012/2/1

Y1 - 2012/2/1

N2 - An extended polypyrazolyl ligand has been used to assemble Mn ions into high spin entities, in the form of one stable molecule composed of two well defined clusters. The slow relaxation of the magnetisation observed is demonstrated to arise from each “half-SMM” composing this molecular cluster pair.

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KW - ligand

KW - magnetisation

KW - molecular cluster pair

U2 - 10.1039/C1CC15682A

DO - 10.1039/C1CC15682A

M3 - Article

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VL - 48

SP - 1413

EP - 1415

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets

Abstract

Keywords

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A molecular [Mn₁₄] coordination cluster featuring two slowly relaxing nanomagnets