A mixed iron(III)/lithium alkoxide

H.R.L. Barley, A.R. Kennedy, R.E. Mulvey

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The heterometallic alkoxide catena-poly[[tetra-mu(2)-tert-butoxo-1: 2 kappa(4) O: O; 1: 3 kappa(4) O: O-bis( tetrahydrofuran)-2 kappa O,3 kappa O-iron(III)dilithium( I)]-mu-bromo], [FeLi2Br(C4H9O)(4)(C4H8O)(2)](n), forms a one-dimensional chain through an a-glide. This conformation is achieved through the formation of Fe-III/O/Li/O rings and Li - Br - Li bridges.
LanguageEnglish
PagesM346-M347
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume61
Issue number7
DOIs
Publication statusPublished - 7 Jul 2005

Fingerprint

O rings
Lithium
Conformations
Iron
tetrahydrofuran

Keywords

  • crystallography
  • aloxides

Cite this

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title = "A mixed iron(III)/lithium alkoxide",
abstract = "The heterometallic alkoxide catena-poly[[tetra-mu(2)-tert-butoxo-1: 2 kappa(4) O: O; 1: 3 kappa(4) O: O-bis( tetrahydrofuran)-2 kappa O,3 kappa O-iron(III)dilithium( I)]-mu-bromo], [FeLi2Br(C4H9O)(4)(C4H8O)(2)](n), forms a one-dimensional chain through an a-glide. This conformation is achieved through the formation of Fe-III/O/Li/O rings and Li - Br - Li bridges.",
keywords = "crystallography, aloxides",
author = "H.R.L. Barley and A.R. Kennedy and R.E. Mulvey",
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A mixed iron(III)/lithium alkoxide. / Barley, H.R.L.; Kennedy, A.R.; Mulvey, R.E.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 61, No. 7, 07.07.2005, p. M346-M347.

Research output: Contribution to journalArticle

TY - JOUR

T1 - A mixed iron(III)/lithium alkoxide

AU - Barley, H.R.L.

AU - Kennedy, A.R.

AU - Mulvey, R.E.

PY - 2005/7/7

Y1 - 2005/7/7

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AB - The heterometallic alkoxide catena-poly[[tetra-mu(2)-tert-butoxo-1: 2 kappa(4) O: O; 1: 3 kappa(4) O: O-bis( tetrahydrofuran)-2 kappa O,3 kappa O-iron(III)dilithium( I)]-mu-bromo], [FeLi2Br(C4H9O)(4)(C4H8O)(2)](n), forms a one-dimensional chain through an a-glide. This conformation is achieved through the formation of Fe-III/O/Li/O rings and Li - Br - Li bridges.

KW - crystallography

KW - aloxides

UR - http://journals.iucr.org/c/issues/2005/07/00/sf1003/sf1003.pdf

UR - http://dx.doi.org/10.1107/S0108270105017555

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DO - 10.1107/S0108270105017555

M3 - Article

VL - 61

SP - M346-M347

JO - Acta Crystallographica Section C: Crystal Structure Communications

T2 - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

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