In situ 31P NMR spectroscopic studies of the reaction of the primary diphosphine 1,2-(PH2)2-C6H4 with the mixed-metal base system nBuLi/Sb(NMe2)3, combined with X-ray structural investigations, strongly support a mechanism involving a series of deprotonation steps followed by antimony-mediated reductive C-P bond cleavage. The central intermediate in this reaction is the tetraphosphide dianion [C6H4P2]22- () from which the final products, the 1,2,3-triphospholide anion [C6H4P3]- (3) and [PhPHLi] (8·Li), are evolved. An EPR spectrocopic study suggests that homolytic C-P bond cleavage is likely to be involved in this final step.
- spectroscopic studies
- c-p bond cleavage
Edge, R., Less, R. J., Naseri, V., McInnes, E. J. L., Mulvey, R. E., & Wright, D. S. (2008). A mechanistic study of the c-p bond cleavage reaction of 1,2-(ph2)(2)-c6h4 with (buli)-bu-n/sb(nme2)(3). Dalton Transactions, (45), 6454-6460. https://doi.org/10.1039/b810028d