Abstract
Ammonolysis of alkyl acetoacetates with 15% NH3 in water at room temperature initially lead to formation of alkyl β-aminocrotonates which slowly converted into 1,5-dimethyl-2,6,9-triaza-bicyclo[3.3.1]nonane-3,7-dione as the main product.
Original language | English |
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Pages (from-to) | 55-60 |
Number of pages | 5 |
Journal | Tetrahedron |
Volume | 58 |
Issue number | 1 |
DOIs | |
Publication status | Published - 27 Nov 2001 |
Keywords
- Ammonolysis
- alkyl acetoacetates
- temperature
- aminocrotonates