A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii)

Moya A. Hay, Arup Sarkar, Gavin A. Craig, Katie E. R. Marriott, Claire Wilson, Gopalan Rajaraman, Mark Murrie

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)
3 Downloads (Pure)

Abstract

The first trigonal bipyramidal Fe(ii) complex to display slow relaxation of magnetisation has been isolated, with this behaviour found to arise through a combination of a large magnetic anisotropy (D = −27.5 cm−1) and a pseudo-D3h symmetry at the Fe(ii) centre, as investigated through ab initio and magnetic studies.
Original languageEnglish
Pages (from-to)6826-6829
Number of pages4
JournalChemical Communications
Volume56
Issue number50
Early online date6 May 2020
DOIs
Publication statusPublished - 25 Jun 2020

Keywords

  • magnetic properties
  • Coordination chemistry
  • magnetic anisotropy

Fingerprint Dive into the research topics of 'A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii)'. Together they form a unique fingerprint.

Cite this