A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii)

Moya A. Hay, Arup Sarkar, Gavin A. Craig, Katie E. R. Marriott, Claire Wilson, Gopalan Rajaraman, Mark Murrie

Research output: Contribution to journalArticle

Abstract

The first trigonal bipyramidal Fe(ii) complex to display slow relaxation of magnetisation has been isolated, with this behaviour found to arise through a combination of a large magnetic anisotropy (D = −27.5 cm−1) and a pseudo-D3h symmetry at the Fe(ii) centre, as investigated through ab initio and magnetic studies.
Original languageEnglish
Pages (from-to)6826-6829
Number of pages4
JournalChemical Communications
Volume56
Issue number50
Early online date6 May 2020
DOIs
Publication statusPublished - 25 Jun 2020

Keywords

  • magnetic properties
  • Coordination chemistry
  • magnetic anisotropy

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    Hay, M. A., Sarkar, A., Craig, G. A., Marriott, K. E. R., Wilson, C., Rajaraman, G., & Murrie, M. (2020). A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii). Chemical Communications, 56(50), 6826-6829. https://doi.org/10.1039/D0CC02382E