A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate)

Gavin A. Craig; Christopher H. Woodall; Scott C. McKellar; Michael R. Probert; Konstantin V. Kamenev; Stephen A. Moggach; Euan K. Brechin; Simon Parsons; Mark Murrie

doi:10.1039/C5DT03320A

A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate)

Gavin A. Craig, Christopher H. Woodall, Scott C. McKellar, Michael R. Probert, Konstantin V. Kamenev, Stephen A. Moggach, Euan K. Brechin, Simon Parsons, Mark Murrie

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Abstract

The crystal structure and magnetic properties of the compound Na5[Mn(l-tart)2]·12H2O (1, l-tart = l-tartrate) have been investigated over the pressure range 0.34–3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

Original language	English
Pages (from-to)	18324-18328
Number of pages	5
Journal	Dalton Transactions
Volume	44
Issue number	42
Early online date	30 Sept 2015
DOIs	https://doi.org/10.1039/C5DT03320A
Publication status	Published - 14 Nov 2015

Keywords

magnetic anisotropy
hydrostatic pressure
crystallography

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title = "A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate)",

abstract = "The crystal structure and magnetic properties of the compound Na5[Mn(l-tart)2]·12H2O (1, l-tart = l-tartrate) have been investigated over the pressure range 0.34–3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.",

keywords = "magnetic anisotropy, hydrostatic pressure, crystallography",

author = "Craig, {Gavin A.} and Woodall, {Christopher H.} and McKellar, {Scott C.} and Probert, {Michael R.} and Kamenev, {Konstantin V.} and Moggach, {Stephen A.} and Brechin, {Euan K.} and Simon Parsons and Mark Murrie",

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doi = "10.1039/C5DT03320A",

language = "English",

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TY - JOUR

T1 - A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate)

AU - Craig, Gavin A.

AU - Woodall, Christopher H.

AU - McKellar, Scott C.

AU - Probert, Michael R.

AU - Kamenev, Konstantin V.

AU - Moggach, Stephen A.

AU - Brechin, Euan K.

AU - Parsons, Simon

AU - Murrie, Mark

PY - 2015/11/14

Y1 - 2015/11/14

N2 - The crystal structure and magnetic properties of the compound Na5[Mn(l-tart)2]·12H2O (1, l-tart = l-tartrate) have been investigated over the pressure range 0.34–3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

AB - The crystal structure and magnetic properties of the compound Na5[Mn(l-tart)2]·12H2O (1, l-tart = l-tartrate) have been investigated over the pressure range 0.34–3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

KW - magnetic anisotropy

KW - hydrostatic pressure

KW - crystallography

U2 - 10.1039/C5DT03320A

DO - 10.1039/C5DT03320A

M3 - Article

SN - 1477-9226

VL - 44

SP - 18324

EP - 18328

JO - Dalton Transactions

JF - Dalton Transactions

IS - 42

ER -

A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate)

Abstract

Keywords

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