A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate)

Gavin A. Craig, Christopher H. Woodall, Scott C. McKellar, Michael R. Probert, Konstantin V. Kamenev, Stephen A. Moggach, Euan K. Brechin, Simon Parsons, Mark Murrie

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The crystal structure and magnetic properties of the compound Na5[Mn(l-tart)2]·12H2O (1, l-tart = l-tartrate) have been investigated over the pressure range 0.34–3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.
LanguageEnglish
Pages18324-18328
Number of pages5
JournalDalton Transactions
Volume44
Issue number42
Early online date30 Sep 2015
DOIs
Publication statusPublished - 14 Nov 2015

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Magnetic anisotropy
Magnetic properties
Crystal structure
Elastic moduli
Ions
tartaric acid

Keywords

  • magnetic anisotropy
  • hydrostatic pressure
  • crystallography

Cite this

Craig, G. A., Woodall, C. H., McKellar, S. C., Probert, M. R., Kamenev, K. V., Moggach, S. A., ... Murrie, M. (2015). A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate). Dalton Transactions, 44(42), 18324-18328. https://doi.org/10.1039/C5DT03320A
Craig, Gavin A. ; Woodall, Christopher H. ; McKellar, Scott C. ; Probert, Michael R. ; Kamenev, Konstantin V. ; Moggach, Stephen A. ; Brechin, Euan K. ; Parsons, Simon ; Murrie, Mark. / A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate). In: Dalton Transactions. 2015 ; Vol. 44, No. 42. pp. 18324-18328.
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abstract = "The crystal structure and magnetic properties of the compound Na5[Mn(l-tart)2]·12H2O (1, l-tart = l-tartrate) have been investigated over the pressure range 0.34–3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.",
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Craig, GA, Woodall, CH, McKellar, SC, Probert, MR, Kamenev, KV, Moggach, SA, Brechin, EK, Parsons, S & Murrie, M 2015, 'A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate)' Dalton Transactions, vol. 44, no. 42, pp. 18324-18328. https://doi.org/10.1039/C5DT03320A

A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate). / Craig, Gavin A.; Woodall, Christopher H.; McKellar, Scott C.; Probert, Michael R.; Kamenev, Konstantin V.; Moggach, Stephen A.; Brechin, Euan K.; Parsons, Simon; Murrie, Mark.

In: Dalton Transactions, Vol. 44, No. 42, 14.11.2015, p. 18324-18328.

Research output: Contribution to journalArticle

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T1 - A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate)

AU - Craig, Gavin A.

AU - Woodall, Christopher H.

AU - McKellar, Scott C.

AU - Probert, Michael R.

AU - Kamenev, Konstantin V.

AU - Moggach, Stephen A.

AU - Brechin, Euan K.

AU - Parsons, Simon

AU - Murrie, Mark

PY - 2015/11/14

Y1 - 2015/11/14

N2 - The crystal structure and magnetic properties of the compound Na5[Mn(l-tart)2]·12H2O (1, l-tart = l-tartrate) have been investigated over the pressure range 0.34–3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

AB - The crystal structure and magnetic properties of the compound Na5[Mn(l-tart)2]·12H2O (1, l-tart = l-tartrate) have been investigated over the pressure range 0.34–3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

KW - magnetic anisotropy

KW - hydrostatic pressure

KW - crystallography

U2 - 10.1039/C5DT03320A

DO - 10.1039/C5DT03320A

M3 - Article

VL - 44

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