A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol

Christophe Audouard; Maxime R Garayt; Erwan Kerouredan; Jonathan Percy; Hongli Yang

doi:10.1016/j.jfluchem.2005.01.005

A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol

Christophe Audouard, Maxime R Garayt, Erwan Kerouredan, Jonathan Percy, Hongli Yang

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol via dehydrofluorination/metallation procedures, followed by thermal [3,3]-sigmatropic rearrangement of the intermediate vinylmetals. The scope and limitations of ether synthesis and dehydrofluorination/metallation are described.

Original language	English
Pages (from-to)	609–621
Number of pages	13
Journal	Journal of Fluorine Chemistry
Volume	126
Issue number	4
DOIs	https://doi.org/10.1016/j.jfluchem.2005.01.005
Publication status	Published - Apr 2005

Keywords

Trifluoroethanol
Difluoro
Acylsilane
Dehydrofluorination/metallation
Synthesis

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10.1016/j.jfluchem.2005.01.005

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title = "A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol",

abstract = "α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol via dehydrofluorination/metallation procedures, followed by thermal [3,3]-sigmatropic rearrangement of the intermediate vinylmetals. The scope and limitations of ether synthesis and dehydrofluorination/metallation are described.",

keywords = "Trifluoroethanol, Difluoro, Acylsilane, Dehydrofluorination/metallation, Synthesis",

author = "Christophe Audouard and Garayt, \{Maxime R\} and Erwan Kerouredan and Jonathan Percy and Hongli Yang",

year = "2005",

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doi = "10.1016/j.jfluchem.2005.01.005",

language = "English",

volume = "126",

pages = " 609–621",

journal = "Journal of Fluorine Chemistry",

publisher = "Elsevier B.V.",

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T1 - A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol

AU - Audouard, Christophe

AU - Garayt, Maxime R

AU - Kerouredan, Erwan

AU - Percy, Jonathan

AU - Yang, Hongli

PY - 2005/4

Y1 - 2005/4

N2 - α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol via dehydrofluorination/metallation procedures, followed by thermal [3,3]-sigmatropic rearrangement of the intermediate vinylmetals. The scope and limitations of ether synthesis and dehydrofluorination/metallation are described.

AB - α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol via dehydrofluorination/metallation procedures, followed by thermal [3,3]-sigmatropic rearrangement of the intermediate vinylmetals. The scope and limitations of ether synthesis and dehydrofluorination/metallation are described.

KW - Trifluoroethanol

KW - Difluoro

KW - Acylsilane

KW - Dehydrofluorination/metallation

KW - Synthesis

U2 - 10.1016/j.jfluchem.2005.01.005

DO - 10.1016/j.jfluchem.2005.01.005

M3 - Article

VL - 126

SP - 609

EP - 621

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 4

ER -

A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol

Abstract

Keywords

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