A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol

Christophe Audouard, Maxime R Garayt, Erwan Kerouredan, Jonathan Percy, Hongli Yang

Research output: Contribution to journalArticle

Abstract

α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol via dehydrofluorination/metallation procedures, followed by thermal [3,3]-sigmatropic rearrangement of the intermediate vinylmetals. The scope and limitations of ether synthesis and dehydrofluorination/metallation are described.
LanguageEnglish
Pages 609–621
Number of pages13
JournalJournal of Fluorine Chemistry
Volume126
Issue number4
DOIs
Publication statusPublished - Apr 2005

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Trifluoroethanol
Ethers
ether
Ether
ethers
Hot Temperature
routes
synthesis

Keywords

  • Trifluoroethanol
  • Difluoro
  • Acylsilane
  • Dehydrofluorination/metallation
  • Synthesis

Cite this

Audouard, Christophe ; Garayt, Maxime R ; Kerouredan, Erwan ; Percy, Jonathan ; Yang, Hongli. / A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol. In: Journal of Fluorine Chemistry. 2005 ; Vol. 126, No. 4. pp. 609–621.
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Audouard, C, Garayt, MR, Kerouredan, E, Percy, J & Yang, H 2005, 'A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol' Journal of Fluorine Chemistry, vol. 126, no. 4, pp. 609–621. https://doi.org/10.1016/j.jfluchem.2005.01.005

A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol. / Audouard, Christophe; Garayt, Maxime R; Kerouredan, Erwan; Percy, Jonathan; Yang, Hongli.

In: Journal of Fluorine Chemistry, Vol. 126, No. 4, 04.2005, p. 609–621.

Research output: Contribution to journalArticle

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AU - Garayt, Maxime R

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AU - Percy, Jonathan

AU - Yang, Hongli

PY - 2005/4

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KW - Trifluoroethanol

KW - Difluoro

KW - Acylsilane

KW - Dehydrofluorination/metallation

KW - Synthesis

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