Abstract
Allyl ethers of trifluoroethanol are transformed to difluorinated analogues of deoxysugars via concise sequences involving dehydrofluorination/metallation, [3,3]-Claisen rearrangement, reduction, and RCM, affording cyclohexenediol substrates for dihydroxylation reactions.
| Original language | English |
|---|---|
| Pages (from-to) | 3903-3918 |
| Number of pages | 15 |
| Journal | Synthesis |
| Issue number | 24 |
| Publication status | Published - 16 Dec 2008 |
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Keywords
- carbasugars
- cyclitols
- difluorinated
- metathesis
- dihydroxylation
Cite this
Kerouredan, E., Percy, J. M., Rinaudo, G., & Singh, K. (2008). A concise route to difluorinated analogues of cyclitols and sugars. Synthesis, (24), 3903-3918.