A concise route to difluorinated analogues of cyclitols and sugars

E. Kerouredan; J.M. Percy; G. Rinaudo; K. Singh

A concise route to difluorinated analogues of cyclitols and sugars

E. Kerouredan, J.M. Percy, G. Rinaudo, K. Singh

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Allyl ethers of trifluoroethanol are transformed to difluorinated analogues of deoxysugars via concise sequences involving dehydrofluorination/metallation, [3,3]-Claisen rearrangement, reduction, and RCM, affording cyclohexenediol substrates for dihydroxylation reactions.

Original language	English
Pages (from-to)	3903-3918
Number of pages	15
Journal	Synthesis
Issue number	24
Publication status	Published - 16 Dec 2008

Keywords

carbasugars
cyclitols
difluorinated
metathesis
dihydroxylation

Access to Document

http://www.thieme-chemistry.com/fileadmin/Thieme/Journals/Synthesis/pdf/toc/inhsynth200824.pdf

Fingerprint Dive into the research topics of 'A concise route to difluorinated analogues of cyclitols and sugars'. Together they form a unique fingerprint.

1 Finished

Physical Organic Chemistry: Opportunities In Synthesis, Materials And Pharmaceuticals (Science And Innovation Award)
Murphy, J., Coombs, G., Ferguson, A. & Florence, A.
Scottish Funding Council SFC, EPSRC (Engineering and Physical Sciences Research Council)
1/09/07 → 30/10/12
Project: Research

Cite this

@article{269beddf04a146459c4bc6870bdce2a1,

title = "A concise route to difluorinated analogues of cyclitols and sugars",

abstract = "Allyl ethers of trifluoroethanol are transformed to difluorinated analogues of deoxysugars via concise sequences involving dehydrofluorination/metallation, [3,3]-Claisen rearrangement, reduction, and RCM, affording cyclohexenediol substrates for dihydroxylation reactions.",

keywords = "carbasugars, cyclitols, difluorinated, metathesis, dihydroxylation",

author = "E. Kerouredan and J.M. Percy and G. Rinaudo and K. Singh",

note = "No contact email found.",

year = "2008",

month = dec,

day = "16",

language = "English",

pages = "3903--3918",

journal = "Synthesis",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

number = "24",

}

TY - JOUR

T1 - A concise route to difluorinated analogues of cyclitols and sugars

AU - Kerouredan, E.

AU - Percy, J.M.

AU - Rinaudo, G.

AU - Singh, K.

N1 - No contact email found.

PY - 2008/12/16

Y1 - 2008/12/16

N2 - Allyl ethers of trifluoroethanol are transformed to difluorinated analogues of deoxysugars via concise sequences involving dehydrofluorination/metallation, [3,3]-Claisen rearrangement, reduction, and RCM, affording cyclohexenediol substrates for dihydroxylation reactions.

AB - Allyl ethers of trifluoroethanol are transformed to difluorinated analogues of deoxysugars via concise sequences involving dehydrofluorination/metallation, [3,3]-Claisen rearrangement, reduction, and RCM, affording cyclohexenediol substrates for dihydroxylation reactions.

KW - carbasugars

KW - cyclitols

KW - difluorinated

KW - metathesis

KW - dihydroxylation

UR - http://www.thieme-chemistry.com/fileadmin/Thieme/Journals/Synthesis/pdf/toc/inhsynth200824.pdf

M3 - Article

SP - 3903

EP - 3918

JO - Synthesis

JF - Synthesis

SN - 0039-7881

IS - 24

ER -

A concise route to difluorinated analogues of cyclitols and sugars

Abstract

Keywords

Access to Document

Physical Organic Chemistry: Opportunities In Synthesis, Materials And Pharmaceuticals (Science And Innovation Award)

Cite this