A 3D interlocked structure from a 2D template: structural requirements for the assembly of a square-planar metal-coordinated [2]rotaxane

A M  Fuller; D A  Leigh; P J  Lusby; I D H  Oswald; S  Parsons; D B  Walker

doi:10.1002/anie.200353622

A 3D interlocked structure from a 2D template: structural requirements for the assembly of a square-planar metal-coordinated [2]rotaxane

A M Fuller, D A Leigh, P J Lusby, I D H Oswald, S Parsons, D B Walker

Strathclyde Institute Of Pharmacy And Biomedical Sciences

Research output: Contribution to journal › Article › peer-review

129 Citations (Scopus)

Abstract

The synthesis of a three-dimensional interlocked molecular architecture (a rotaxane) from a two-dimensional square-planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking.

Original language	English
Pages (from-to)	3914-3918
Number of pages	5
Journal	Agewandte Chemie-International Edition
Volume	43
Issue number	30
Early online date	20 Jul 2004
DOIs	https://doi.org/10.1002/anie.200353622
Publication status	Published - 26 Jul 2004

Keywords

coordination modes
palladium
rotaxanes
template synthesis
transition-metal
incorporating cucurbituril
thermodynamic control
crystal-structures
complexes
bonds
refinement
catenanes
molecules

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10.1002/anie.200353622

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abstract = "The synthesis of a three-dimensional interlocked molecular architecture (a rotaxane) from a two-dimensional square-planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking. ",

keywords = "coordination modes, palladium, rotaxanes, template synthesis, transition-metal, incorporating cucurbituril, thermodynamic control, crystal-structures, complexes, bonds, refinement, catenanes, molecules",

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T2 - structural requirements for the assembly of a square-planar metal-coordinated [2]rotaxane

AU - Fuller, A M

AU - Leigh, D A

AU - Lusby, P J

AU - Oswald, I D H

AU - Parsons, S

AU - Walker, D B

PY - 2004/7/26

Y1 - 2004/7/26

N2 - The synthesis of a three-dimensional interlocked molecular architecture (a rotaxane) from a two-dimensional square-planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking.

AB - The synthesis of a three-dimensional interlocked molecular architecture (a rotaxane) from a two-dimensional square-planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking.

KW - coordination modes

KW - palladium

KW - rotaxanes

KW - template synthesis

KW - transition-metal

KW - incorporating cucurbituril

KW - thermodynamic control

KW - crystal-structures

KW - complexes

KW - bonds

KW - refinement

KW - catenanes

KW - molecules

U2 - 10.1002/anie.200353622

DO - 10.1002/anie.200353622

M3 - Article

SN - 1433-7851

VL - 43

SP - 3914

EP - 3918

JO - Agewandte Chemie-International Edition

JF - Agewandte Chemie-International Edition

IS - 30

ER -

A 3D interlocked structure from a 2D template: structural requirements for the assembly of a square-planar metal-coordinated [2]rotaxane

Abstract

Keywords

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