A 3D interlocked structure from a 2D template

structural requirements for the assembly of a square-planar metal-coordinated [2]rotaxane

A M Fuller, D A Leigh, P J Lusby, I D H Oswald, S Parsons, D B Walker

Research output: Contribution to journalArticle

112 Citations (Scopus)

Abstract

The synthesis of a three-dimensional interlocked molecular architecture (a rotaxane) from a two-dimensional square-planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking.
Original languageEnglish
Pages (from-to)3914-3918
Number of pages5
JournalAgewandte Chemie-International Edition
Volume43
Issue number30
Early online date20 Jul 2004
DOIs
Publication statusPublished - 26 Jul 2004

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Rotaxanes
Metals

Keywords

  • coordination modes
  • palladium
  • rotaxanes
  • template synthesis
  • transition-metal
  • incorporating cucurbituril
  • thermodynamic control
  • crystal-structures
  • complexes
  • bonds
  • refinement
  • catenanes
  • molecules

Cite this

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title = "A 3D interlocked structure from a 2D template: structural requirements for the assembly of a square-planar metal-coordinated [2]rotaxane",
abstract = "The synthesis of a three-dimensional interlocked molecular architecture (a rotaxane) from a two-dimensional square-planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking.",
keywords = "coordination modes, palladium, rotaxanes, template synthesis, transition-metal, incorporating cucurbituril, thermodynamic control, crystal-structures, complexes, bonds, refinement, catenanes, molecules",
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A 3D interlocked structure from a 2D template : structural requirements for the assembly of a square-planar metal-coordinated [2]rotaxane. / Fuller, A M ; Leigh, D A ; Lusby, P J ; Oswald, I D H ; Parsons, S ; Walker, D B .

In: Agewandte Chemie-International Edition, Vol. 43, No. 30, 26.07.2004, p. 3914-3918.

Research output: Contribution to journalArticle

TY - JOUR

T1 - A 3D interlocked structure from a 2D template

T2 - structural requirements for the assembly of a square-planar metal-coordinated [2]rotaxane

AU - Fuller, A M

AU - Leigh, D A

AU - Lusby, P J

AU - Oswald, I D H

AU - Parsons, S

AU - Walker, D B

PY - 2004/7/26

Y1 - 2004/7/26

N2 - The synthesis of a three-dimensional interlocked molecular architecture (a rotaxane) from a two-dimensional square-planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking.

AB - The synthesis of a three-dimensional interlocked molecular architecture (a rotaxane) from a two-dimensional square-planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking.

KW - coordination modes

KW - palladium

KW - rotaxanes

KW - template synthesis

KW - transition-metal

KW - incorporating cucurbituril

KW - thermodynamic control

KW - crystal-structures

KW - complexes

KW - bonds

KW - refinement

KW - catenanes

KW - molecules

U2 - 10.1002/anie.200353622

DO - 10.1002/anie.200353622

M3 - Article

VL - 43

SP - 3914

EP - 3918

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 30

ER -