A 100 kHz pulse shaping 2D-IR spectrometer based on dual Yb:KGW amplifiers

P.M. Donaldson, G.M. Greetham, D.J. Shaw, A.W. Parker, M. Towrie

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Abstract

A high-speed, high-sensitivity and compact two-dimensional infrared (2D-IR) spectrometer based on 100 kHz Yb:KGW regenerative amplifier technology is described and demonstrated. The setup is three color, using an independent pump OPA and two separately tunable probe OPAs. The spectrometer uses 100 kHz acousto-optic pulse shaping on the pump beam for rapid 2D-IR acquisitions. The shot-to-shot stability of the laser system yields excellent signal-to-noise figures (∼10 μOD noise on 5000 laser shots). We show that the reduced bandwidth of the Yb:KGW amplifiers in comparison with conventional Ti:sapphire systems does not compromise the ability of the setup to generate high-quality 2D-IR data. Instrument responses of <300 fs are demonstrated and 2D-IR data presented for several systems of interest to physical chemists, showing spectral diffusion in NaSCN, amide I and II bands of a β sheet protein and DNA base-pair–backbone couplings. Overall, the increased data acquisition speed, intrinsic stability, and robustness of the Yb:KGW lasers are a significant step forward for 2D-IR spectroscopy.
Original languageEnglish
Pages (from-to)780–787
Number of pages8
JournalJournal of Physical Chemistry A
Volume122
Issue number3
Early online date18 Dec 2017
DOIs
Publication statusPublished - 25 Jan 2018

Keywords

  • infrared spectroscopy
  • 2D-IR spectroscopy
  • tunable light

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    Donaldson, P. M., Greetham, G. M., Shaw, D. J., Parker, A. W., & Towrie, M. (2018). A 100 kHz pulse shaping 2D-IR spectrometer based on dual Yb:KGW amplifiers. Journal of Physical Chemistry A, 122(3), 780–787. https://doi.org/10.1021/acs.jpca.7b10259