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2019
1 Citation (Scopus)
20 Downloads (Pure)

Alkali metal effects in trans-metal-trapping (TMT): comparing LiTMP with NaTMP in cooperative MTMP/Ga(CH2SiMe3)3 metalation reactions

McLellan, R., Uzelac, M., Bole, L. J., Gil-Negrete, J. M., Armstrong, D. R., Kennedy, A. R., Mulvey, R. E. & Hevia, E., 15 Jan 2019, In : Synthesis. 51, 05, p. 1207-1215 9 p.

Research output: Contribution to journalArticle

Open Access
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Alkali Metals
Alkali metals
Metals
Diamines
anisole
9 Citations (Scopus)

Alkali-metal-mediated synergistic effects in polar main group organometallic chemistry

Robertson, S. D., Uzelac, M. & Mulvey, R. E., 19 Mar 2019, In : Chemical Reviews. 119, 14, p. 8332-8405 74 p.

Research output: Contribution to journalArticle

Alkali Metals
Organometallics
Metals
Nucleophiles
Gallium

Backbone reactivity of lithium β-Diketiminate (NacNac) complexes with CO 2, tBuNCO and iPrNCO

Gauld, R. M., McLellan, R., Kennedy, A. R., Barker, J., Reid, J. & Mulvey, R. E., 18 Nov 2019, In : Chemistry - A European Journal. 25, 64, p. 14728-14734 7 p.

Research output: Contribution to journalArticle

Carbon Monoxide
Lithium
Dimers
Amides
Lithium Compounds
1 Citation (Scopus)
8 Downloads (Pure)
Open Access
File
Nitrogen fixation
Alkali Metals
Anhydrides
Alkali metals
Lithium
11 Downloads (Pure)
Open Access
File
Alkynes
Lithium
Nuclear magnetic resonance
Deprotonation
X ray crystallography

Selective mono- and dimetallation of a group 3 sandwich complex

Martínez-Martínez, A. J., Kennedy, A. R., Paprocki, V., Fantuzzi, F., Dewhurst, R. D., O'Hara, C. T., Braunschweig, H. & Mulvey, R. E., 21 Aug 2019, In : Chemical Communications. 55, 65, p. 9677-9680 4 p.

Research output: Contribution to journalArticle

Scandium
Deprotonation
Lithium
Amides
Metals
Discrete Fourier transforms
Atoms
Quantum theory
Electronic structure
Anions
2018
24 Citations (Scopus)
21 Downloads (Pure)
Open Access
File
Aluminum
Lithium
Catalysis
Ligands
Catalysts
1 Citation (Scopus)
1 Downloads (Pure)

Contrasting synergistic heterobimetallic (Na-Mg) and homometallic (Na or Mg) bases in metalation reactions of dialkylphenylphosphines and dialkylanilines: lateral vs ring selectivities

Stevens, MI. A., Hashim, F. H., Gwee, E. S. H., Izgorodina, E. I., Mulvey, R. E. & Blair, V. L., 17 Oct 2018, In : Chemistry - A European Journal. 24, 58, p. 15669-15677 8 p.

Research output: Contribution to journalArticle

Open Access
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Thymidine Monophosphate
Regioselectivity
Substrates
Sodium
Deprotonation
17 Citations (Scopus)
18 Downloads (Pure)

Donor-influenced structure-activity correlations in stoichiometric and catalytic reactions of lithium monoamido-monohydrido-dialkylaluminates

Lemmerz, L. E., McLellan, R., Judge, N. R., Kennedy, A. R., Orr, S. A., Uzelac, M., Hevia, E., Robertson, S. D., Okuda, J. & Mulvey, R. E., 11 Jul 2018, In : Chemistry - A European Journal. 24, 39, p. 9940-9948 9 p.

Research output: Contribution to journalArticle

Open Access
File
hydroboration
constitution
Ketones
Lithium
ketones
43 Citations (Scopus)
28 Downloads (Pure)
Open Access
File
Triazoles
Ketones
Aldehydes
Lithium
4,4,5,5-tetramethyl(1,3,2)dioxaborolane
8 Citations (Scopus)
19 Downloads (Pure)

Trans-metal-trapping: concealed crossover complexes en route to transmetallation?

Uzelac, M. & Mulvey, R. E., 4 Jun 2018, In : Chemistry - A European Journal. 24, 31, p. 7786-7793 8 p.

Research output: Contribution to journalLiterature review

Open Access
File
Metals
Organometallic Compounds
Gallium
Organometallics
Aluminum
2017
17 Citations (Scopus)
23 Downloads (Pure)
Open Access
File
Dihydropyridines
Alkali Metals
Alkali metals
Lithium
Hydrides
3 Citations (Scopus)
20 Downloads (Pure)

Benzene submits to main-group power

Mulvey, R. E., 1 Dec 2017, In : Science. 358, 6367, p. 1132 1 p.

Research output: Contribution to journalShort survey

Open Access
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Benzene
11 Downloads (Pure)
Open Access
File
Metals
Sodium
X rays
Ether
Alkali Metals
12 Citations (Scopus)
79 Downloads (Pure)
Open Access
File
Boranes
Diamines
Ruthenium
Cyclization
Dehydrogenation
17 Citations (Scopus)
60 Downloads (Pure)
Open Access
File
Metals
Molecules
Cross Reactions
Organometallics
Ketones
2016
3 Citations (Scopus)
75 Downloads (Pure)
Open Access
File
Dihydropyridines
Hydrides
Dimers
Alkali Metals
Thermoanalysis
11 Citations (Scopus)
69 Downloads (Pure)

Exposing elusive cationic magnesium-chloro aggregates in aluminate complexes through donor control

Brouillet, E. V., Kennedy, A. R., Koszinowski, K., McLellan, R., Mulvey, R. E. & Robertson, S. D., 7 Apr 2016, In : Dalton Transactions. 45, 13, p. 5590-5597 8 p.

Research output: Contribution to journalArticle

Open Access
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Magnesium
Electrolytes
Secondary batteries
Anions
2-methyltetrahydrofuran
11 Downloads (Pure)

Revealing the remarkable structural diversity of the alkali metal transfer agents of the trans-calix[2]benzene[2]pyrrolidide ligand

Fuentes, M. Á., Martínez-Martínez, A. J., Kennedy, A. R. & Mulvey, R. E., 21 Oct 2016, In : Chemical Communications. 52, 82, p. 12199-12201 3 p.

Research output: Contribution to journalArticle

Open Access
File
Alkali Metals
Alkali metals
Organometallics
Benzene
Lithium
8 Citations (Scopus)
63 Downloads (Pure)
Open Access
File
Alkali Metals
Alkali metals
Amides
Ligands
Potassium
11 Citations (Scopus)
33 Downloads (Pure)

Tetraamine Me6TREN induced monomerization of alkali metal borohydrides and aluminohydrides

Kennedy, A. R., McLellan, R., McNeil, G. J., Mulvey, R. E. & Robertson, S. D., 8 Jan 2016, In : Polyhedron. 103A, p. 94-99 6 p.

Research output: Contribution to journalArticle

Open Access
File
Alkali Metals
Borohydrides
borohydrides
Alkali metals
Hydrides
23 Citations (Scopus)
75 Downloads (Pure)

Transforming LiTMP lithiation of challenging diazines via gallium alkyl trans-metal-trapping

Uzelac, M., Kennedy, A. R., Hevia, E. & Mulvey, R. E., 20 Sep 2016, In : Angewandte Chemie International Edition. 55, p. 13147-13150 4 p.

Research output: Contribution to journalArticle

Open Access
File
Pyrazines
Deprotonation
Gallium
pyrazines
pyrimidines