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2019
1 Citation (Scopus)
20 Downloads (Pure)

Alkali metal effects in trans-metal-trapping (TMT): comparing LiTMP with NaTMP in cooperative MTMP/Ga(CH2SiMe3)3 metalation reactions

McLellan, R., Uzelac, M., Bole, L. J., Gil-Negrete, J. M., Armstrong, D. R., Kennedy, A. R., Mulvey, R. E. & Hevia, E., 15 Jan 2019, In : Synthesis. 51, 05, p. 1207-1215 9 p.

Research output: Contribution to journalArticle

Open Access
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Alkali Metals
Alkali metals
Metals
Diamines
anisole
9 Citations (Scopus)

Alkali-metal-mediated synergistic effects in polar main group organometallic chemistry

Robertson, S. D., Uzelac, M. & Mulvey, R. E., 19 Mar 2019, In : Chemical Reviews. 119, 14, p. 8332-8405 74 p.

Research output: Contribution to journalArticle

Alkali Metals
Organometallics
Metals
Nucleophiles
Gallium

Backbone reactivity of lithium β-Diketiminate (NacNac) complexes with CO 2, tBuNCO and iPrNCO

Gauld, R. M., McLellan, R., Kennedy, A. R., Barker, J., Reid, J. & Mulvey, R. E., 18 Nov 2019, In : Chemistry - A European Journal. 25, 64, p. 14728-14734 7 p.

Research output: Contribution to journalArticle

Carbon Monoxide
Lithium
Dimers
Amides
Lithium Compounds
1 Citation (Scopus)
8 Downloads (Pure)
Open Access
File
Nitrogen fixation
Alkali Metals
Anhydrides
Alkali metals
Lithium
11 Downloads (Pure)
Open Access
File
Alkynes
Lithium
Nuclear magnetic resonance
Deprotonation
X ray crystallography

Selective mono- and dimetallation of a group 3 sandwich complex

Martínez-Martínez, A. J., Kennedy, A. R., Paprocki, V., Fantuzzi, F., Dewhurst, R. D., O'Hara, C. T., Braunschweig, H. & Mulvey, R. E., 21 Aug 2019, In : Chemical Communications. 55, 65, p. 9677-9680 4 p.

Research output: Contribution to journalArticle

Scandium
Deprotonation
Lithium
Amides
Metals
Discrete Fourier transforms
Atoms
Quantum theory
Electronic structure
Anions
2018
24 Citations (Scopus)
21 Downloads (Pure)
Open Access
File
Aluminum
Lithium
Catalysis
Ligands
Catalysts
1 Citation (Scopus)
1 Downloads (Pure)

Contrasting synergistic heterobimetallic (Na-Mg) and homometallic (Na or Mg) bases in metalation reactions of dialkylphenylphosphines and dialkylanilines: lateral vs ring selectivities

Stevens, MI. A., Hashim, F. H., Gwee, E. S. H., Izgorodina, E. I., Mulvey, R. E. & Blair, V. L., 17 Oct 2018, In : Chemistry - A European Journal. 24, 58, p. 15669-15677 8 p.

Research output: Contribution to journalArticle

Open Access
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Thymidine Monophosphate
Regioselectivity
Substrates
Sodium
Deprotonation
17 Citations (Scopus)
18 Downloads (Pure)

Donor-influenced structure-activity correlations in stoichiometric and catalytic reactions of lithium monoamido-monohydrido-dialkylaluminates

Lemmerz, L. E., McLellan, R., Judge, N. R., Kennedy, A. R., Orr, S. A., Uzelac, M., Hevia, E., Robertson, S. D., Okuda, J. & Mulvey, R. E., 11 Jul 2018, In : Chemistry - A European Journal. 24, 39, p. 9940-9948 9 p.

Research output: Contribution to journalArticle

Open Access
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hydroboration
constitution
Ketones
Lithium
ketones
43 Citations (Scopus)
28 Downloads (Pure)
Open Access
File
Triazoles
Ketones
Aldehydes
Lithium
4,4,5,5-tetramethyl(1,3,2)dioxaborolane
8 Citations (Scopus)
19 Downloads (Pure)

Trans-metal-trapping: concealed crossover complexes en route to transmetallation?

Uzelac, M. & Mulvey, R. E., 4 Jun 2018, In : Chemistry - A European Journal. 24, 31, p. 7786-7793 8 p.

Research output: Contribution to journalLiterature review

Open Access
File
Metals
Organometallic Compounds
Gallium
Organometallics
Aluminum
2017
17 Citations (Scopus)
23 Downloads (Pure)
Open Access
File
Dihydropyridines
Alkali Metals
Alkali metals
Lithium
Hydrides
3 Citations (Scopus)
20 Downloads (Pure)

Benzene submits to main-group power

Mulvey, R. E., 1 Dec 2017, In : Science. 358, 6367, p. 1132 1 p.

Research output: Contribution to journalShort survey

Open Access
File
Benzene
11 Downloads (Pure)
Open Access
File
Metals
Sodium
X rays
Ether
Alkali Metals
12 Citations (Scopus)
79 Downloads (Pure)
Open Access
File
Boranes
Diamines
Ruthenium
Cyclization
Dehydrogenation
17 Citations (Scopus)
60 Downloads (Pure)
Open Access
File
Metals
Molecules
Cross Reactions
Organometallics
Ketones
2016
3 Citations (Scopus)
75 Downloads (Pure)
Open Access
File
Dihydropyridines
Hydrides
Dimers
Alkali Metals
Thermoanalysis
11 Citations (Scopus)
69 Downloads (Pure)

Exposing elusive cationic magnesium-chloro aggregates in aluminate complexes through donor control

Brouillet, E. V., Kennedy, A. R., Koszinowski, K., McLellan, R., Mulvey, R. E. & Robertson, S. D., 7 Apr 2016, In : Dalton Transactions. 45, 13, p. 5590-5597 8 p.

Research output: Contribution to journalArticle

Open Access
File
Magnesium
Electrolytes
Secondary batteries
Anions
2-methyltetrahydrofuran
11 Downloads (Pure)

Revealing the remarkable structural diversity of the alkali metal transfer agents of the trans-calix[2]benzene[2]pyrrolidide ligand

Fuentes, M. Á., Martínez-Martínez, A. J., Kennedy, A. R. & Mulvey, R. E., 21 Oct 2016, In : Chemical Communications. 52, 82, p. 12199-12201 3 p.

Research output: Contribution to journalArticle

Open Access
File
Alkali Metals
Alkali metals
Organometallics
Benzene
Lithium
8 Citations (Scopus)
63 Downloads (Pure)
Open Access
File
Alkali Metals
Alkali metals
Amides
Ligands
Potassium
11 Citations (Scopus)
33 Downloads (Pure)

Tetraamine Me6TREN induced monomerization of alkali metal borohydrides and aluminohydrides

Kennedy, A. R., McLellan, R., McNeil, G. J., Mulvey, R. E. & Robertson, S. D., 8 Jan 2016, In : Polyhedron. 103A, p. 94-99 6 p.

Research output: Contribution to journalArticle

Open Access
File
Alkali Metals
Borohydrides
borohydrides
Alkali metals
Hydrides
23 Citations (Scopus)
75 Downloads (Pure)

Transforming LiTMP lithiation of challenging diazines via gallium alkyl trans-metal-trapping

Uzelac, M., Kennedy, A. R., Hevia, E. & Mulvey, R. E., 20 Sep 2016, In : Angewandte Chemie International Edition. 55, p. 13147-13150 4 p.

Research output: Contribution to journalArticle

Open Access
File
Pyrazines
Deprotonation
Gallium
pyrazines
pyrimidines
2015
17 Citations (Scopus)
31 Downloads (Pure)

Adding a structural context to the deprotometalation and trans-metal trapping chemistry of phenyl-substituted benzotriazole

Fuentes, M. Á., Kennedy, A. R., Mulvey, R. E., Parkinson, J. A., Rantanen, T., Robertson, S. D. & Snieckus, V., 12 Oct 2015, In : Chemistry - A European Journal . 21, 42, p. 14812-14822 11 p.

Research output: Contribution to journalArticle

Open Access
File
Organometallics
Isomers
Nuclear magnetic resonance spectroscopy
Extrusion
Quenching
21 Citations (Scopus)
113 Downloads (Pure)

Alkali-metal-mediated magnesiations of an N-heterocyclic carbene: normal, abnormal and "paranormal" reactivity in a single tritopic molecule

Martínez-Martínez, A. J., Fuentes, M. Á., Hernán-Gõmez, A., Hevia, E., Kennedy, A. R., Mulvey, R. E. & O'Hara, C. T., 16 Nov 2015, In : Angewandte Chemie International Edition. 54, 47, p. 14075-14079 5 p.

Research output: Contribution to journalArticle

Open Access
File
Alkali Metals
Alkali metals
Thymidine Monophosphate
Sodium
Atoms
12 Citations (Scopus)
72 Downloads (Pure)

Developing lithium chemistry of 1,2-dihydropyridines: from kinetic intermediates to isolable characterized compounds

Armstrong, D. R., Harris, C. M. M., Kennedy, A. R., Liggat, J. J., McLellan, R., Mulvey, R. E., Urquhart, M. D. T. & Robertson, S. D., 2015, In : Chemistry - A European Journal. 21, 41, p. 14410-14420 11 p.

Research output: Contribution to journalArticle

Open Access
File
Dihydropyridines
Lithium
Pyridine
Kinetics
Addition reactions
26 Citations (Scopus)
103 Downloads (Pure)
Open Access
File
Alkanes
Lithium
Hydrides
Isomers
Paraffins
10 Citations (Scopus)
72 Downloads (Pure)
Open Access
File
Thymidine Monophosphate
Crystalline materials
Lewis Bases
N,N-dimethylphenylethylamine
Lithium
25 Citations (Scopus)
75 Downloads (Pure)

Structurally defined zincated and aluminated complexes of ferrocene made by alkali-metal-synergistic syntheses

Clegg, W., Crosbie, E., Dale-Black, S. H., Hevia, E., Honeyman, G. W., Kennedy, A. R., Mulvey, R. E., Ramsay, D. L. & Robertson, S. D., 2015, In : Organometallics. 34, 11, p. 2580-2589 10 p.

Research output: Contribution to journalArticle

Open Access
File
Thymidine Monophosphate
Alkali Metals
alkali metals
lithium
sodium
2014
8 Citations (Scopus)
203 Downloads (Pure)

Dehydromethylation of alkali metal salts of the utility amide 2,2,6,6-tetramethylpiperidide (TMP)

Kennedy, A. R., Leenhouts, S. M., Liggat, J. J., Martínez-Martínez, A. J., Miller, K., Mulvey, R. E., O'Hara, C. T., O'Keefe, P. & Steven, A., 21 Sep 2014, In : Chemical Communications. 50, 73, p. 10588-10591 4 p.

Research output: Contribution to journalArticle

Open Access
File
Alkali Metals
Thermolysis
Methane
Alkali metals
Amides
92 Citations (Scopus)
368 Downloads (Pure)

Directed ortho-meta'- and meta-meta'-dimetalations: a template base approach to deprotonation

Martínez-Martínez, A. J., Kennedy, A. R., Mulvey, R. E. & O'Hara, C. T., 14 Nov 2014, In : Science. 346, 6211, p. 834-837 4 p.

Research output: Contribution to journalArticle

Open Access
File
Benzene
Amides

Di-tert-butylzinc

Mulvey, R. E. & Garden, J. A., 20 Oct 2014, e-EROS encyclopedia of reagents for organic synthesis. New Jersey, p. 1-4 4 p.

Research output: Chapter in Book/Report/Conference proceedingEntry for encyclopedia/dictionary

4 Citations (Scopus)

Donor-activated alkali metal dipyridylamides: co-complexation reactions with zinc alkyls and reactivity studies with benzophenone

Armstrong, D. R., Brouillet, E. V., Kennedy, A. R., Garden, J. A., Granitzka, M., Mulvey, R. E. & Trivett, J. J., 14 Oct 2014, In : Dalton Transactions. 43, 38, p. 14409-14423 15 p.

Research output: Contribution to journalArticle

Alkali Metals
Complexation
Zinc
Alkylation
Crystalline materials

FascinATES: mixed-metal ate compounds that function synergistically

Mulvey, R. E. & Robertson, S. D., 2014, Organo-di-Metallic Compounds (or Reagents): Synergistic Effects and Synthetic Applications. Xi, Z. (ed.). Springer, p. 129-158 30 p. (Topics in Organometallic Chemistry; vol. 47).

Research output: Chapter in Book/Report/Conference proceedingChapter (peer-reviewed)

Metals
Atoms
24 Citations (Scopus)
48 Downloads (Pure)

Lithium, sodium and potassium picolyl complexes: syntheses, structures and bonding

Kennedy, A. R., Mulvey, R. E., Urquhart, R. I. & Robertson, S. D., 14 Oct 2014, In : Dalton Transactions. 43, 38, p. 14265-14274 10 p.

Research output: Contribution to journalArticle

Open Access
File
Picolines
Lithium
Potassium
Metals
Sodium
44 Citations (Scopus)
217 Downloads (Pure)

Organozinc pivalate reagents: segregation, solubility, stabilisation and structural insights

Hernan-Gomez, A., Herd, E., Hevia, E., Kennedy, A., Knochel, P., Koszinowski, K., Manolikakes, S. M., Schnegelsberg, C. & Mulvey, R., 3 Mar 2014, In : Angewandte Chemie International Edition. 53, p. 2706–2710 5 p.

Research output: Contribution to journalArticle

Open Access
File
Stabilization
Solubility
Organometallics
Salts
Air
38 Citations (Scopus)
106 Downloads (Pure)

Pre-inverse-crowns: synthetic, structural and reactivity studies of alkali metal magnesiates primed for inverse crown formation

Martinez-Martinez, A. J., Armstrong, D. R., Conway, B., Fleming, B. J., Klett, J., Kennedy, A. R., Mulvey, R. E., Robertson, S. D. & O'Hara, C. T., 1 Feb 2014, In : Chemical Science. 5, 2, p. 771-781 11 p.

Research output: Contribution to journalArticle

Open Access
File
Thymidine Monophosphate
Alkali Metals
Atoms
Potassium Compounds
Ligands
2 Citations (Scopus)
48 Downloads (Pure)
Open Access
File
interception
Amides
Isomers
amides
isomers
46 Citations (Scopus)
272 Downloads (Pure)

TMP (2,2,6,6-tetramethylpiperidide)-aluminate bases: lithium-mediated alumination or lithiation-alkylaluminium-trapping reagents?

Armstrong, D. R., Crosbie, E., Hevia, E., Mulvey, R. E., Ramsay, D. L. & Robertson, S. D., 1 Aug 2014, In : Chemical Science. 5, 8, p. 3031-3045 15 p.

Research output: Contribution to journalArticle

Open Access
File
Lithium
Hexanes
2,2,6,6-tetramethylpiperidide
Substrates
Aluminum
2013
10 Citations (Scopus)
86 Downloads (Pure)

A hetero-alkali-metal version of the utility amide LDA: lithium-potassium diisopropylamide

Armstrong, D. R., Kennedy, A. R., Mulvey, R. E. & Robertson, S. D., 2013, In : Dalton Transactions. 42, 10, p. 3704-3711 8 p.

Research output: Contribution to journalArticle

Open Access
File
Alkali Metals
Lithium
Amides
Potassium
Nuclear magnetic resonance
61 Citations (Scopus)

An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry

Mulvey, R. E., 2013, In : Dalton Transactions. 42, 19, p. 6676-6693 18 p.

Research output: Contribution to journalArticle

Alkali Metals
Anions
Metals
Lewis Bases
Lewis Acids
28 Citations (Scopus)
94 Downloads (Pure)
Open Access
File
Polymorphism
Lithium
Nuclear magnetic resonance
X rays
Thymidine Monophosphate
11 Citations (Scopus)
Lewis Bases
Thymidine Monophosphate
Deprotonation
Complexation
Amides
6 Citations (Scopus)

Donor-activated lithiation and sodiation of trifluoromethylbenzene: structural, spectroscopic and theoretical insights

Garden, J., Armstrong, D., Clegg, W., Garcia Alvarez, J., Hevia, E., Kennedy, A., Mulvey, R., Robertson, S. & Russo, L., 2013, In : Organometallics. 32, 19, p. 5481-5490 10 p.

Research output: Contribution to journalArticle

reaction intermediates
constitution
products
Regioselectivity
Deprotonation
21 Citations (Scopus)
58 Downloads (Pure)

Evaluating cis-2,6-dimethylpiperidide (cis-DMP) as a base component in lithium-mediated zincation chemistry

Armstrong, D. R., Garden, J. A., Kennedy, A. R., Leenhouts, S. M., Mulvey, R. E., O'Keefe, P., O'Hara, C. T. & Steven, A., 27 Sep 2013, In : Chemistry - A European Journal. 19, 40, p. 13492-13503 12 p.

Research output: Contribution to journalArticle

Open Access
File
Lithium
Amides
Deprotonation
X ray crystallography
Alkali metals
30 Citations (Scopus)

Modern developments in magnesium reagent chemistry for synthesis

Mulvey, R. E. & Robertson, S. D., 2013, Alkaline-Earth Metal Compounds: Oddities and Applications. Harder, S. (ed.). Springer, p. 103-140 38 p. (Topics in Organometallic Chemistry; vol. 45).

Research output: Chapter in Book/Report/Conference proceedingChapter (peer-reviewed)

Open Access
File
Magnesium
13 Citations (Scopus)
35 Downloads (Pure)

Modifying alkylzinc reactivity with 2,2 '-dipyridylamide: activation of tBu-Zn bonds for para-alkylation of benzophenone

Armstrong, D. R., Garden, J. A., Kennedy, A. R., Mulvey, R. & Robertson, S. D., 8 Jul 2013, In : Angewandte Chemie International Edition. 52, 28, p. 7190-7193 4 p.

Research output: Contribution to journalArticle

Open Access
File
Alkylation
Amides
Sodium
Chemical activation
benzophenone

Molecular architecture and synergy in organometallic chemistry

Mulvey, R., Oct 2013, Molecular Aesthetics. Weibel, P. & Fruk, L. (eds.). p. 408-424 16 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

26 Citations (Scopus)
70 Downloads (Pure)

Monomerizing alkali-metal 3,5-dimethylbenzyl salts with tris(N, N -dimethyl-2-aminoethyl)amine (MeTREN): structural and bonding implications

Armstrong, D. R., Davidson, M. G., Garcia-Vivo, D., Kennedy, A. R., Mulvey, R. E. & Robertson, S. D., 2 Oct 2013, In : Inorganic Chemistry. 52, 20, p. 12023-12032 10 p.

Research output: Contribution to journalArticle

Open Access
File
Alkali Metals
alkali metals
Amines
potassium
Potassium
3 Citations (Scopus)

Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone

Clegg, W., Fleming, B. J., Garcia-Alvarez, P., Hogg, L. M., Kennedy, A. R., Klett, J., Martinez-Martinez, A. J., Mulvey, R. E., Russo, L. & O'Hara, C. T., 2013, In : Dalton Transactions. 42, 7, p. 2512-2519 8 p.

Research output: Contribution to journalArticle

Alkali Metals
Aromatization
X ray crystallography
Coordination Complexes
Organometallics