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Author

  • Alan Kennedy

Structural studies of cesium, lithium/cesium and sodium/cesium bis(trimethylsilyl)amide (HMDS) complexes

Ojeda Amador, A. I., Martínez-Martínez, A. J., Kennedy, A. R. & O'Hara, C. T., 13 May 2016, In : Inorganic Chemistry. 55, 11, p. 5719–5728 10 p.

Research output: Contribution to journalArticle

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12 Citations (Scopus)
86 Downloads (Pure)

Structural studies of (rac)-BIPHEN organomagnesiates and intermediates in the halogen-metal exchange of 2-Bromopyridine

Francos, J., Gros, P. C., Kennedy, A. R. & O'Hara, C. T., 8 Jun 2015, In : Organometallics. 34, 11, p. 2550-2557 8 p.

Research output: Contribution to journalArticle

Open Access
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2 Citations (Scopus)
36 Downloads (Pure)

Structurally powered synergic 2,2,6,6-tetramethylpiperidine bimetallics: new reflections through lithium-mediated ortho aluminations

Mulvey, R., Armstrong, D. R., Conway, B., Crosbie, E., Kennedy, A. & Robertson, S., 19 Dec 2011, In : Inorganic Chemistry. 50, 24, p. 12241-12251 11 p.

Research output: Contribution to journalArticle

35 Citations (Scopus)

Structurally defined zincated and aluminated complexes of ferrocene made by alkali-metal-synergistic syntheses

Clegg, W., Crosbie, E., Dale-Black, S. H., Hevia, E., Honeyman, G. W., Kennedy, A. R., Mulvey, R. E., Ramsay, D. L. & Robertson, S. D., 2015, In : Organometallics. 34, 11, p. 2580-2589 10 p.

Research output: Contribution to journalArticle

Open Access
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26 Citations (Scopus)
80 Downloads (Pure)

Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone

Clegg, W., Fleming, B. J., Garcia-Alvarez, P., Hogg, L. M., Kennedy, A. R., Klett, J., Martinez-Martinez, A. J., Mulvey, R. E., Russo, L. & O'Hara, C. T., 2013, In : Dalton Transactions. 42, 7, p. 2512-2519 8 p.

Research output: Contribution to journalArticle

3 Citations (Scopus)
Open Access
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10 Citations (Scopus)
63 Downloads (Pure)

Structural and synthetic insights into pyridine homocouplings mediated by a β-diketiminato magnesium amide complex

Hevia, E., McLellan, R., Davin, L., Clegg, W., Kennedy, A. & Probert, M. R., 27 Jul 2018, In : Chemistry - A European Journal. 7 p.

Research output: Contribution to journalArticle

Open Access
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6 Citations (Scopus)

Structural and reactivity insights in Mg–Zn hybrid chemistry: Zn–I exchange and Pd-catalysed cross-coupling applications of aromatic substrates

Bluemke, T. D., Clegg, W., García-Alvarez, P., Kennedy, A. R., Koszinowski, K., McCall, M. D., Russo, L. & Hevia, E., 1 Sep 2014, In : Chemical Science. 5, 9, p. 3552-3562 11 p.

Research output: Contribution to journalArticle

Open Access
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18 Citations (Scopus)
81 Downloads (Pure)

Structural and metal-halogen exchange reactivity studies of sodium magnesiate biphenolate complexes

Yeardley, C., Kennedy, A. R., Gros, P. C., Touchet, S., Fairley, M., McLellan, R., Martínez-Martínez, A. J. & O'Hara, C. T., 28 Apr 2020, In : Dalton Transactions. 49, 16, p. 5257-5263 7 p.

Research output: Contribution to journalArticle

Structural and mechanistic insights into s-block bimetallic catalysis: sodium magnesiate-catalyzed guanylation of amines

De Tullio, M., Hernán-Gómez, A., Livingstone, Z., Clegg, W., Kennedy, A. R., Harrington, R. W., Antiñolo, A., Martínez, A., Carrillo-Hermosilla, F. & Hevia, E., 5 Dec 2016, In : Chemistry - A European Journal. 22, 49, p. 17646-17656 11 p.

Research output: Contribution to journalArticle

Open Access
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17 Citations (Scopus)
34 Downloads (Pure)

Structural and magnetic diversity in alkali-metal Manganate chemistry: evaluating donor and alkali-metal effects in co-complexation processes

Uzelac, M., Borilovic, I., Amores, M., Cadenbach, T., Kennedy, A. R., Aromí, G. & Hevia, E., 24 Feb 2016, In : Chemistry - A European Journal . 22, 14, p. 4843-4854 12 p.

Research output: Contribution to journalArticle

Open Access
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3 Citations (Scopus)
53 Downloads (Pure)

Stereoselective synthesis of alkylidene phthalides

Dragan, A., Jones, D. H., Kennedy, A. R. & Tomkinson, N. C. O., 17 Jul 2016, In : Organic Letters. 18, p. 3086-3089 4 p.

Research output: Contribution to journalArticle

Open Access
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5 Citations (Scopus)
40 Downloads (Pure)

Speciation control during Suzuki-Miyaura cross-coupling of haloaryl and haloalkenyl MIDA boronic esters

Fyfe, J. W. B., Valverde, E., Seath, C. P., Kennedy, A. R., Redmond, J. M., Anderson, N. A. & Watson, A. J. B., 8 Jun 2015, In : Chemistry - A European Journal. 21, 24, p. 8951–8964 14 p.

Research output: Contribution to journalArticle

Open Access
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25 Citations (Scopus)
290 Downloads (Pure)

Solid state and solution studies of lithium tris(n-butyl)magnesiates stabilised by Lewis donors

Zaragoza-Calero, S., Francos, J., Kennedy, A. R. & O'Hara, C. T., 9 Mar 2015, In : Dalton Transactions. 44, 16, p. 7258-7267 10 p.

Research output: Contribution to journalArticle

Open Access
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6 Citations (Scopus)
139 Downloads (Pure)

Soft scorpionate coordination at alkali metals

Rajesekharan-Nair, R., Lutta, S. T., Kennedy, A. R., Reglinski, J. & Spicer, M. D., May 2014, In : Acta Crystallographica Section C: Structural Chemistry. 70, 5, p. 421-427 7 p.

Research output: Contribution to journalArticle

5 Citations (Scopus)

Soft Scorpionate anions as platforms for novel heterocycles

Rajasekharan Nair, R., Marckwordt, A., Lutta, S., Schwalbe, M., Biernat, A., Armstrong, D., Watson, A., Kennedy, A., Reglinski, J. & Spicer, M., 2013, In : Chemistry - A European Journal . 19, 40, p. 13561–13568

Research output: Contribution to journalArticle

9 Citations (Scopus)

Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone

Armstrong, D. R., Balloch, L., Crawford, J. J., Fleming, B. J., Hogg, L. M., Kennedy, A. R., Klett, J., Mulvey, R. E., O'Hara, C. T., Orr, S. A. & Robertson, S., 2012, In : Chemical Communications. 48, 10, p. 1541-1543 3 p.

Research output: Contribution to journalArticle

16 Citations (Scopus)

Shedding new light on ZnCl2-mediated addition reactions of Grignard reagents to ketones: structural authentication of key intermediates and diffusion-ordered NMR studies

Armstrong, D. R., Clegg, W., Garcia-Alvarez, P., McCall, M. D., Nuttall, L., Kennedy, A. R., Russo, L. & Hevia, E., 11 Apr 2011, In : Chemistry - A European Journal. 17, 16, p. 4470-4479 10 p.

Research output: Contribution to journalArticle

38 Citations (Scopus)

Sequential Norrish Type II photoelimination and intramolecular Aldol cyclization of alpha-diketones: synthesis of polyhydroxylated cyclopentitols by ring contraction of hexopyranose carbohydrate derivatives

Alvarez-Dorta, D., Leon, E. I., Kennedy, A., Martin, A., Perez-Martin, I., Riesco-Fagundo, C. & Suarez, E., 29 Jul 2013, In : Chemistry - A European Journal . 19, 31, p. 10312-10333 22 p.

Research output: Contribution to journalArticle

7 Citations (Scopus)

Self-assembled π-conjugated organic nanoplates: from hexagonal to triangular motifs

Martinez-Tong, D. E., Gbabode, G., Ruzie, C., Chattopadhyay, B., Schweicher, G., Kennedy, A. R., Geerts, Y. H. & Sferrazza, M., 4 Dec 2016, In : RSC Advances. 6, 50, p. 44921-44931 11 p.

Research output: Contribution to journalArticle

Open Access
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1 Citation (Scopus)
46 Downloads (Pure)

Selective mono- and dimetallation of a group 3 sandwich complex

Martínez-Martínez, A. J., Kennedy, A. R., Paprocki, V., Fantuzzi, F., Dewhurst, R. D., O'Hara, C. T., Braunschweig, H. & Mulvey, R. E., 21 Aug 2019, In : Chemical Communications. 55, 65, p. 9677-9680 4 p.

Research output: Contribution to journalArticle

Open Access
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Scope and limitations of a DMF bio-alternative within Sonogashira cross-coupling and Cacchi-type annulation

Wilson, K., Kennedy, A., Murray, J., Greatex, B., Jamieson, C. & Watson, A., 8 Sep 2016, In : Beilstein Journal of Organic Chemistry . 12, p. 2005-2011 7 p.

Research output: Contribution to journalArticle

Open Access
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32 Citations (Scopus)
357 Downloads (Pure)

Scalable total synthesis and comprehensive structure–activity relationship studies of the phytotoxin coronatine

Littleson, M. M., Baker, C. M., Dalencon, A. J., Frye, E. C., Jamieson, C., Kennedy, A. R., Ling, K. B., McLachlan, M. M., Montgomery, M. G., Russell, C. J. & Watson, A. J. B., 13 Feb 2018, (Accepted/In press) In : Nature Communications. 14 p.

Research output: Contribution to journalArticle

Open Access
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62 Downloads (Pure)

Salt forms of the pharmaceutical amide dihydrocarbamazepine

Buist, A. & Kennedy, A., 1 Feb 2016, In : Acta Crystallographica Section C: Structural Chemistry. 72, 2, p. 155-160 6 p.

Research output: Contribution to journalArticle

Open Access
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2 Citations (Scopus)
95 Downloads (Pure)

Salt forms of sulfadiazine with alkali metal and organic cations

Campbell, G., Fisher, R., Kennedy, A. R., King, N. L. C. & Spiteri, R., 15 Mar 2018, In : Acta Crystallographica Section C: Structural Chemistry. 74, 4, p. 472-479 8 p.

Research output: Contribution to journalArticle

Open Access
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28 Downloads (Pure)

Salt forms of amides: protonation and polymorphism of carbamazepine and cytenamide

Buist, A., Kennedy, A., Shankland, K., Shankland, N. & Spillman, M. J., 2013, In : Crystal Growth and Design. 13, 11, p. 5121-5127 7 p.

Research output: Contribution to journalArticle

13 Citations (Scopus)

Salt and ionic cocrystalline forms of amides: protonation of carbamazepine in aqueous media

Buist, A. R., Edgeley, D. S., Kabova, E. A., Kennedy, A. R., Hooper, D., Rollo, D. G., Shankland, K. & Spillman, M. J., 28 Oct 2015, In : Crystal Growth and Design. 15, p. 5955-5962 8 p.

Research output: Contribution to journalArticle

Open Access
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5 Citations (Scopus)
17 Downloads (Pure)

Role of H‑optimization in the computed intermolecular interactions and charge-transfer integrals in diketopyrrolopyrroles

Calvo-Castro, J., Kennedy, A. R. & McHugh, C. J., 11 Apr 2019, In : Journal of Physical Chemistry A. 123, 14, p. 3185-3193 9 p.

Research output: Contribution to journalArticle

Open Access
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1 Citation (Scopus)

Revealing the remarkable structural diversity of the alkali metal transfer agents of the trans-calix[2]benzene[2]pyrrolidide ligand

Fuentes, M. Á., Martínez-Martínez, A. J., Kennedy, A. R. & Mulvey, R. E., 21 Oct 2016, In : Chemical Communications. 52, 82, p. 12199-12201 3 p.

Research output: Contribution to journalArticle

Open Access
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13 Downloads (Pure)

Remote functionalisation via sodium alkylamidozincate intermediates: access to unusual fluorenone and pyridyl ketone reactivity patterns

Crawford, J. J., Fleming, B. J., Kennedy, A. R., Klett, J., O'Hara, C. T. & Orr, S. A., 11 Jan 2011, In : Chemical Communications (London). 47, 13, p. 3772-3774 3 p.

Research output: Contribution to journalArticle

Open Access
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15 Citations (Scopus)
88 Downloads (Pure)
Open Access
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4 Citations (Scopus)
22 Downloads (Pure)

Regioselective magnesiation of N-heterocyclic molecules: securing insecure cyclic anions by a β-diketiminate-magnesium clamp

Davin, L., McLellan, R., Hernán-Gómez, A., Clegg, B., Kennedy, A. R., Stepek, I., Mertens, M. & Hevia, E., 1 Sep 2017, In : Chemical Communications. 4 p.

Research output: Contribution to journalArticle

Open Access
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15 Citations (Scopus)
12 Downloads (Pure)
19 Citations (Scopus)

Redetermination of 3-methylbenzoic acid

Moreno-Fuquen, R., De Almeida Santos, R. & Kennedy, A. R., Mar 2011, In : Acta Crystallographica Section E: Structure Reports. 67, p. O569-U1282 12 p.

Research output: Contribution to journalArticle

Open Access
4 Citations (Scopus)

Readily accessible chiral at nitrogen cage structures

Rowley, J., Yau, S. C., Kariuki, B. M., Kennedy, A. & Tomkinson, N., 6 Mar 2013, In : Organic and Biomolecular Chemistry. 11, 13, p. 2198-2205 8 p.

Research output: Contribution to journalArticle

4 Citations (Scopus)

Reactivity of phosphine- and thioether-tethered N-heterocyclic carbenes with ruthenium carbonyl

Cabeza, J. A., Damonte, M., Garcia-Alvarez, P., Guadalupe Hernandez-Cruz, M. & Kennedy, A., 9 Jan 2012, In : Organometallics. 31, 1, p. 327-334 8 p.

Research output: Contribution to journalArticle

28 Citations (Scopus)

Reactivity of [Ru-3(CO)(12)] with a phosphine-functionalized Imidazol-2-ylidene and Its imidazolium salt

Cabeza, J. A., Damonte, M., Garcia-Alvarez, P., Kennedy, A. & Perez-Carreno, E., 28 Feb 2011, In : Organometallics. 30, 4, p. 826-833 8 p.

Research output: Contribution to journalArticle

40 Citations (Scopus)

Rational synthesis of normal, abnormal and anionic NHC-gallium alkyl complexes: structural, stability and isomerization insights

Uzelac, M., Hernán-Gómez, A., Armstrong, D. R., Kennedy, A. R. & Hevia, E., 1 Oct 2015, In : Chemical Science. 6, 10, p. 5719-5728 10 p.

Research output: Contribution to journalArticle

Open Access
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18 Citations (Scopus)
92 Downloads (Pure)

Radical-mediated C–H functionalization: a strategy for access to modified cyclodextrins

Alvarez-Dorta, D., León, E. I., Kennedy, A. R., Martin, A., Pérez-Martín, I. & Suárez, E., 2 Nov 2016, In : Journal of Organic Chemistry. 81, 23, p. 11766-11787 22 p.

Research output: Contribution to journalArticle

Open Access
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4 Citations (Scopus)
6 Downloads (Pure)

Probing the metallating ability of a polybasic sodium alkylmagnesiate supported by a bulky bis(amido) ligand: deprotomagnesiation reactions of nitrogen-based aromatic substrates

Armstrong, D. R., Clegg, W., Hernan-Gomez, A., Kennedy, A. R., Livingstone, Z., Robertson, S. D., Russo, L. & Hevia, E., 21 Mar 2014, In : Dalton Transactions. 43, 11, p. 4361-4369 9 p.

Research output: Contribution to journalArticle

10 Citations (Scopus)

Presence of π…π and C-H…π interactions in the new Schiff base 2- {(E)-[(3-tert-butyl-1-phenyl-1H-pyrazol-5-yl)imino]methyl}phenol: experimental and DFT computational studies

Moreno-Fuquen, R., Cuenú, F., Torres, J. E., De la Vega, G., Galarza, E., Abonia, R. & Kennedy, A. R., 15 Dec 2017, In : Journal of Molecular Structure . 1150, p. 366-373 8 p.

Research output: Contribution to journalArticle

Open Access
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4 Citations (Scopus)
14 Downloads (Pure)

Preparation of polyfunctional arylzinc organometallics in toluene by halogen/zinc exchange reactions

Balkenhohl, M., Ziegler, D. S., Desaintjean, A., Bole, L. J., Kennedy, A. R., Hevia, E. & Knochel, P., 9 Sep 2019, In : Angewandte Chemie International Edition. 58, 37, p. 12898-12902 5 p.

Research output: Contribution to journalArticle

Open Access
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3 Citations (Scopus)

Potassium-alkyl magnesiates: synthesis, structures and Mg-H exchange applications of aromatic and heterocyclic substrates

Baillie, S. E., Bluemke, T. D., Clegg, W., Kennedy, A. R., Klett, J., Russo, L., De Tullio, M. & Hevia, E., 3 Sep 2014, In : Chemical Communications. 50, p. 12859-12862 4 p.

Research output: Contribution to journalArticle

Open Access
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17 Citations (Scopus)
84 Downloads (Pure)

Polymorphism in bulk and thin films: the curious case of dithiophene-DPP(Boc)-dithiophene

Salammal, S. T., Balandier, J-Y., Arlin, J-B., Olivier, Y., Lemaur, V., Wang, L., Beljonne, D., Cornil, J., Kennedy, A. R., Geerts, Y. H. & Chattopadhyay, B., 9 Jan 2014, In : Journal of Physical Chemistry C. 118, 1, p. 657-669 13 p.

Research output: Contribution to journalArticle

23 Citations (Scopus)

Photochemistry of α-Diketones in carbohydrates: anomalous Norrish typeII photoelimination and Norrish-Yang photocyclization promoted the internal carbonyl group

Alvarez-Dorta, D., León, E. I., Kennedy, A. R., Martín, A., Pérez-Martín, I., Riesco-Fagundo, C. & Suárez, E., 17 Jan 2014, In : Chemistry - A European Journal. 20, p. 2663-2671

Research output: Contribution to journalArticle

8 Citations (Scopus)

Oxidative addition of aryl halides and phenol derivatives to a prototypical nickel(0) complex

Bajo Velazquez, S., Laidlaw, G., Kennedy, A., Sproules, S. & Nelson, D., 12 Jul 2017.

Research output: Contribution to conferencePoster

Oxidative addition of aryl electrophiles to a prototypical nickel(0) complex: mechanism and structure/reactivity relationships

Bajo, S., Laidlaw, G., Kennedy, A. R., Sproules, S. & Nelson, D. J., 24 Apr 2017, In : Organometallics. 36, 8, p. 1662-1672 11 p.

Research output: Contribution to journalArticle

Open Access
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54 Citations (Scopus)
82 Downloads (Pure)

Oxacycle fused [1]benzothieno[3,2‐b][1]benzothiophene derivatives: synthesis, electronic structure, electrochemical properties, ionisation potential, and crystal structure

Mohankumar, M., Chattopadhyay, B., Sanguinet, L., Kennedy, A. R., Lemaur, V., Cornil, J., Fenwick, O., Samori, P., Geerts, Y. & Hadji, R., 2 Oct 2018, In : ChemPlusChem.

Research output: Contribution to journalArticle

Open Access
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2 Downloads (Pure)

Organozinc pivalate reagents: segregation, solubility, stabilisation and structural insights

Hernán-Gómez, A., Herd, E., Hevia, E., Kennedy, A. R., Knochel, P., Koszinowski, K., Manolikakes, S. M., Mulvey, R. E. & Schnegelsberg, C., 3 Mar 2014, In : Angewandte Chemie International Edition. 53, 10, p. 2706–2710 5 p.

Research output: Contribution to journalArticle

Open Access
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45 Citations (Scopus)
220 Downloads (Pure)