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Abstract
The asymmetric unit of the title compound, C16H34N42+ center dot- 2I(-) center dot 2H(2)O, contains one half-cation, one iodide anion and one water molecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster of 15 cations and a comparison of the hydrogen bonding suggests that this compound is isostructural with its bromide analogue. Intermolecular hydrogen bonding forms eight-membered [H-OH center dot center dot center dot I](2) and [H-N-H center dot center dot center dot I](2) rings and creates a sheet structure.
Original language | English |
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Pages (from-to) | o682-o683 |
Number of pages | 2 |
Journal | Acta Crystallographica Section E: Structure Reports |
Volume | 67 |
Issue number | 3 |
DOIs | |
Publication status | Published - Mar 2011 |
Keywords
- macrocyclic ligands
- complex
- crystal
- nickel
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Dive into the research topics of '5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate'. Together they form a unique fingerprint.Projects
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