5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate

Alan R. Kennedy; S.T. Lutta; Catriona A. Morrison; M.O. Okoth; D.M. Orang'o

doi:10.1107/S1600536811005848

5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate

Alan R. Kennedy, S.T. Lutta, Catriona A. Morrison, M.O. Okoth, D.M. Orang'o

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

The asymmetric unit of the title compound, C16H34N42+ center dot- 2I(-) center dot 2H(2)O, contains one half-cation, one iodide anion and one water molecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster of 15 cations and a comparison of the hydrogen bonding suggests that this compound is isostructural with its bromide analogue. Intermolecular hydrogen bonding forms eight-membered [H-OH center dot center dot center dot I](2) and [H-N-H center dot center dot center dot I](2) rings and creates a sheet structure.

Original language	English
Pages (from-to)	o682-o683
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports
Volume	67
Issue number	3
DOIs	https://doi.org/10.1107/S1600536811005848
Publication status	Published - Mar 2011

Keywords

macrocyclic ligands
complex
crystal
nickel

Access to Document

10.1107/S1600536811005848Licence: CC BY 4.0

Link to publication in Scopus

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Physical Organic Chemistry: Opportunities In Synthesis, Materials And Pharmaceuticals (Science And Innovation Award)
Murphy, J., Coombs, G., Ferguson, A. & Florence, A.
Scottish Funding Council SFC, EPSRC (Engineering and Physical Sciences Research Council)
1/09/07 → 30/10/12
Project: Research

x-ray diffractometer
Alan Kennedy (Manager)
Pure And Applied Chemistry
Facility/equipment: Equipment

Cite this

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title = "5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate",

abstract = "The asymmetric unit of the title compound, C16H34N42+ center dot- 2I(-) center dot 2H(2)O, contains one half-cation, one iodide anion and one water molecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster of 15 cations and a comparison of the hydrogen bonding suggests that this compound is isostructural with its bromide analogue. Intermolecular hydrogen bonding forms eight-membered [H-OH center dot center dot center dot I](2) and [H-N-H center dot center dot center dot I](2) rings and creates a sheet structure.",

keywords = "macrocyclic ligands, complex, crystal, nickel",

author = "Kennedy, {Alan R.} and S.T. Lutta and Morrison, {Catriona A.} and M.O. Okoth and D.M. Orang'o",

year = "2011",

month = mar,

doi = "10.1107/S1600536811005848",

language = "English",

volume = "67",

pages = "o682--o683 ",

journal = "Acta Crystallographica Section E: Structure Reports",

issn = "1600-5368",

number = "3",

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TY - JOUR

T1 - 5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate

AU - Kennedy, Alan R.

AU - Lutta, S.T.

AU - Morrison, Catriona A.

AU - Okoth, M.O.

AU - Orang'o, D.M.

PY - 2011/3

Y1 - 2011/3

N2 - The asymmetric unit of the title compound, C16H34N42+ center dot- 2I(-) center dot 2H(2)O, contains one half-cation, one iodide anion and one water molecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster of 15 cations and a comparison of the hydrogen bonding suggests that this compound is isostructural with its bromide analogue. Intermolecular hydrogen bonding forms eight-membered [H-OH center dot center dot center dot I](2) and [H-N-H center dot center dot center dot I](2) rings and creates a sheet structure.

AB - The asymmetric unit of the title compound, C16H34N42+ center dot- 2I(-) center dot 2H(2)O, contains one half-cation, one iodide anion and one water molecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster of 15 cations and a comparison of the hydrogen bonding suggests that this compound is isostructural with its bromide analogue. Intermolecular hydrogen bonding forms eight-membered [H-OH center dot center dot center dot I](2) and [H-N-H center dot center dot center dot I](2) rings and creates a sheet structure.

KW - macrocyclic ligands

KW - complex

KW - crystal

KW - nickel

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U2 - 10.1107/S1600536811005848

DO - 10.1107/S1600536811005848

M3 - Article

VL - 67

SP - o682-o683

JO - Acta Crystallographica Section E: Structure Reports

JF - Acta Crystallographica Section E: Structure Reports

SN - 1600-5368

IS - 3

ER -

5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate

Abstract

Keywords

Access to Document

Physical Organic Chemistry: Opportunities In Synthesis, Materials And Pharmaceuticals (Science And Innovation Award)

x-ray diffractometer

Cite this