Abstract
The asymmetric unit of the title compound, C16H34N42+ center dot- 2I(-) center dot 2H(2)O, contains one half-cation, one iodide anion and one water molecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster of 15 cations and a comparison of the hydrogen bonding suggests that this compound is isostructural with its bromide analogue. Intermolecular hydrogen bonding forms eight-membered [H-OH center dot center dot center dot I](2) and [H-N-H center dot center dot center dot I](2) rings and creates a sheet structure.
| Original language | English |
|---|---|
| Pages (from-to) | o682-o683 |
| Number of pages | 2 |
| Journal | Acta Crystallographica Section E: Structure Reports |
| Volume | 67 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Mar 2011 |
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Keywords
- macrocyclic ligands
- complex
- crystal
- nickel
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5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate. / Kennedy, Alan R.; Lutta, S.T.; Morrison, Catriona A.; Okoth, M.O.; Orang'o, D.M.
In: Acta Crystallographica Section E: Structure Reports, Vol. 67, No. 3, 03.2011, p. o682-o683 .Research output: Contribution to journal › Article
TY - JOUR
T1 - 5,7,7,12,14,14-Hexamethyl-4,8-diaza-1,11-diazoniocyclotetradeca-4,11-diene diiodide dihydrate
AU - Kennedy, Alan R.
AU - Lutta, S.T.
AU - Morrison, Catriona A.
AU - Okoth, M.O.
AU - Orang'o, D.M.
PY - 2011/3
Y1 - 2011/3
N2 - The asymmetric unit of the title compound, C16H34N42+ center dot- 2I(-) center dot 2H(2)O, contains one half-cation, one iodide anion and one water molecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster of 15 cations and a comparison of the hydrogen bonding suggests that this compound is isostructural with its bromide analogue. Intermolecular hydrogen bonding forms eight-membered [H-OH center dot center dot center dot I](2) and [H-N-H center dot center dot center dot I](2) rings and creates a sheet structure.
AB - The asymmetric unit of the title compound, C16H34N42+ center dot- 2I(-) center dot 2H(2)O, contains one half-cation, one iodide anion and one water molecule. The cation has crystallographically imposed centrosymmetric symmetry. Despite some differences in the unit-cell dimensions, packing analysis on a cluster of 15 cations and a comparison of the hydrogen bonding suggests that this compound is isostructural with its bromide analogue. Intermolecular hydrogen bonding forms eight-membered [H-OH center dot center dot center dot I](2) and [H-N-H center dot center dot center dot I](2) rings and creates a sheet structure.
KW - macrocyclic ligands
KW - complex
KW - crystal
KW - nickel
UR - http://www.scopus.com/inward/record.url?scp=79952424787&partnerID=8YFLogxK
U2 - 10.1107/S1600536811005848
DO - 10.1107/S1600536811005848
M3 - Article
VL - 67
SP - o682-o683
JO - Acta Crystallographica Section E: Structure Reports
JF - Acta Crystallographica Section E: Structure Reports
SN - 1600-5368
IS - 3
ER -