4,4 '-(Azinodimethylene)dipyridinium chloranilate dichloromethane disolvate

A R Kennedy, F R N Waterson

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The dichloromethane disolvate of 4,4'-(azinodimethylene)dipyridinium chloranilate, C12H12N42+.C6Cl2O42-.2CH(2)Cl(2), consists of one-dimensional hydrogen-bonded molecular tapes that propagate along the [1(2) over bar 0 120] direction. Both cations and anions lie across centres of inversion. The molecular tapes are planar but do not stack in the expected segregated manner, instead having chloranilate anions sandwiched between azine groups.

LanguageEnglish
PagesO613-O615
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume59
Issue number11
DOIs
Publication statusPublished - Nov 2003

Fingerprint

Methylene Chloride
Tapes
Anions
Cations
Hydrogen
Direction compound

Keywords

  • dichloromethane disolvate
  • one-dimensional hydrogen-bonded molecular tapes
  • planar
  • chloranilate anions sandwiched between azine groups

Cite this

@article{cd991dd84da4438290755c2ecccfea66,
title = "4,4 '-(Azinodimethylene)dipyridinium chloranilate dichloromethane disolvate",
abstract = "The dichloromethane disolvate of 4,4'-(azinodimethylene)dipyridinium chloranilate, C12H12N42+.C6Cl2O42-.2CH(2)Cl(2), consists of one-dimensional hydrogen-bonded molecular tapes that propagate along the [1(2) over bar 0 120] direction. Both cations and anions lie across centres of inversion. The molecular tapes are planar but do not stack in the expected segregated manner, instead having chloranilate anions sandwiched between azine groups.",
keywords = "dichloromethane disolvate, one-dimensional hydrogen-bonded molecular tapes, planar, chloranilate anions sandwiched between azine groups",
author = "Kennedy, {A R} and Waterson, {F R N}",
year = "2003",
month = "11",
doi = "10.1107/S010827010302050X",
language = "English",
volume = "59",
pages = "O613--O615",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
number = "11",

}

4,4 '-(Azinodimethylene)dipyridinium chloranilate dichloromethane disolvate. / Kennedy, A R ; Waterson, F R N .

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 59, No. 11, 11.2003, p. O613-O615.

Research output: Contribution to journalArticle

TY - JOUR

T1 - 4,4 '-(Azinodimethylene)dipyridinium chloranilate dichloromethane disolvate

AU - Kennedy, A R

AU - Waterson, F R N

PY - 2003/11

Y1 - 2003/11

N2 - The dichloromethane disolvate of 4,4'-(azinodimethylene)dipyridinium chloranilate, C12H12N42+.C6Cl2O42-.2CH(2)Cl(2), consists of one-dimensional hydrogen-bonded molecular tapes that propagate along the [1(2) over bar 0 120] direction. Both cations and anions lie across centres of inversion. The molecular tapes are planar but do not stack in the expected segregated manner, instead having chloranilate anions sandwiched between azine groups.

AB - The dichloromethane disolvate of 4,4'-(azinodimethylene)dipyridinium chloranilate, C12H12N42+.C6Cl2O42-.2CH(2)Cl(2), consists of one-dimensional hydrogen-bonded molecular tapes that propagate along the [1(2) over bar 0 120] direction. Both cations and anions lie across centres of inversion. The molecular tapes are planar but do not stack in the expected segregated manner, instead having chloranilate anions sandwiched between azine groups.

KW - dichloromethane disolvate

KW - one-dimensional hydrogen-bonded molecular tapes

KW - planar

KW - chloranilate anions sandwiched between azine groups

U2 - 10.1107/S010827010302050X

DO - 10.1107/S010827010302050X

M3 - Article

VL - 59

SP - O613-O615

JO - Acta Crystallographica Section C: Crystal Structure Communications

T2 - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 11

ER -