4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one

Mehmet Akkurt; Alan R Kennedy; Sabry H H Younes; Shaaban K Mohamed; Antar A Abdelhamid

doi:10.1107/S160053681204651X

4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one

Mehmet Akkurt, Alan R Kennedy, Sabry H H Younes, Shaaban K Mohamed, Antar A Abdelhamid

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

In the title compound, C15H12N2O, the phenyl ring makes a dihedral angle of 32.45 (9)° with the benzene ring of the 1,5-benzodiazepin-2-one unit. The seven-membered ring adopts a boat conformation with the methyl-ene group as the prow and the fused benzene-ring C atoms as the stern. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R2(2)(8) loops. The dimers are further linked by C-H⋯O hydrogen bonds, so forming a column along the a-axis direction.

Original language	English
Article number	o3356
Number of pages	7
Journal	Acta Crystallographica Section E: Structure Reports
Volume	68
Issue number	12
DOIs	https://doi.org/10.1107/S160053681204651X
Publication status	Published - 1 Dec 2012

Keywords

benzene ring
phenyl rings
atoms
molecules
crystal structure

Access to Document

10.1107/S160053681204651X

x-ray diffractometer
Kennedy, A.
Pure And Applied Chemistry
Facility/equipment: Equipment

Cite this

@article{44e9a07f74b54d3c83eaeebee3fee324,

title = "4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one",

abstract = "In the title compound, C15H12N2O, the phenyl ring makes a dihedral angle of 32.45 (9)° with the benzene ring of the 1,5-benzodiazepin-2-one unit. The seven-membered ring adopts a boat conformation with the methyl-ene group as the prow and the fused benzene-ring C atoms as the stern. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R2(2)(8) loops. The dimers are further linked by C-H⋯O hydrogen bonds, so forming a column along the a-axis direction.",

keywords = "benzene ring, phenyl rings, atoms, molecules, crystal structure",

author = "Mehmet Akkurt and Kennedy, {Alan R} and Younes, {Sabry H H} and Mohamed, {Shaaban K} and Abdelhamid, {Antar A}",

year = "2012",

month = dec,

day = "1",

doi = "10.1107/S160053681204651X",

language = "English",

volume = "68",

journal = "Acta Crystallographica Section E: Structure Reports",

issn = "1600-5368",

number = "12",

}

TY - JOUR

T1 - 4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one

AU - Akkurt, Mehmet

AU - Kennedy, Alan R

AU - Younes, Sabry H H

AU - Mohamed, Shaaban K

AU - Abdelhamid, Antar A

PY - 2012/12/1

Y1 - 2012/12/1

N2 - In the title compound, C15H12N2O, the phenyl ring makes a dihedral angle of 32.45 (9)° with the benzene ring of the 1,5-benzodiazepin-2-one unit. The seven-membered ring adopts a boat conformation with the methyl-ene group as the prow and the fused benzene-ring C atoms as the stern. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R2(2)(8) loops. The dimers are further linked by C-H⋯O hydrogen bonds, so forming a column along the a-axis direction.

AB - In the title compound, C15H12N2O, the phenyl ring makes a dihedral angle of 32.45 (9)° with the benzene ring of the 1,5-benzodiazepin-2-one unit. The seven-membered ring adopts a boat conformation with the methyl-ene group as the prow and the fused benzene-ring C atoms as the stern. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R2(2)(8) loops. The dimers are further linked by C-H⋯O hydrogen bonds, so forming a column along the a-axis direction.

KW - benzene ring

KW - phenyl rings

KW - atoms

KW - molecules

KW - crystal structure

U2 - 10.1107/S160053681204651X

DO - 10.1107/S160053681204651X

M3 - Article

C2 - 23476191

SN - 1600-5368

VL - 68

JO - Acta Crystallographica Section E: Structure Reports

JF - Acta Crystallographica Section E: Structure Reports

IS - 12

M1 - o3356

ER -

4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one

Abstract

Keywords

Access to Document

Fingerprint

Equipment

x-ray diffractometer

Cite this