3-Nitro-1-(triisopropylsilyl)-1H-pyrrole

Alan Kennedy; Abedawn I. Khalaf; Colin J. Suckling; Roger D. Waigh

doi:10.1107/S1600536806025943

3-Nitro-1-(triisopropylsilyl)-1H-pyrrole

Alan Kennedy, Abedawn I. Khalaf, Colin J. Suckling, Roger D. Waigh

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The nitration of 1-(triisopropylsilyl)-1H-pyrrole leads to a mixt. of products following partial acid cleavage of the triisopropylsilyl protecting group. Structural detn. showed the isolated products to be 3-nitro-1-(triisopropylsilyl)-1H-pyrrole, C13H24N2O2Si (I), and 2,4-dinitropyrrole. In the solid state, I exists as discrete mols. with only weak C-H...nitro H bonds between them. Crystallog. data are given.

Original language	English
Pages (from-to)	o3282-o3284
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports
Volume	62
Issue number	8
DOIs	https://doi.org/10.1107/S1600536806025943
Publication status	Published - Aug 2006

Keywords

nitration
4-dinitropyrrole
hydrogen bonds

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@article{0810004e485a422296aab2dfd38d6740,

title = "3-Nitro-1-(triisopropylsilyl)-1H-pyrrole",

abstract = "The nitration of 1-(triisopropylsilyl)-1H-pyrrole leads to a mixt. of products following partial acid cleavage of the triisopropylsilyl protecting group. Structural detn. showed the isolated products to be 3-nitro-1-(triisopropylsilyl)-1H-pyrrole, C13H24N2O2Si (I), and 2,4-dinitropyrrole. In the solid state, I exists as discrete mols. with only weak C-H...nitro H bonds between them. Crystallog. data are given. ",

keywords = "nitration, 4-dinitropyrrole , hydrogen bonds",

author = "Alan Kennedy and Khalaf, \{Abedawn I.\} and Suckling, \{Colin J.\} and Waigh, \{Roger D.\}",

year = "2006",

month = aug,

doi = "10.1107/S1600536806025943",

language = "English",

volume = "62",

pages = "o3282--o3284",

journal = "Acta Crystallographica Section E: Structure Reports",

issn = "1600-5368",

number = "8",

}

TY - JOUR

T1 - 3-Nitro-1-(triisopropylsilyl)-1H-pyrrole

AU - Kennedy, Alan

AU - Khalaf, Abedawn I.

AU - Suckling, Colin J.

AU - Waigh, Roger D.

PY - 2006/8

Y1 - 2006/8

N2 - The nitration of 1-(triisopropylsilyl)-1H-pyrrole leads to a mixt. of products following partial acid cleavage of the triisopropylsilyl protecting group. Structural detn. showed the isolated products to be 3-nitro-1-(triisopropylsilyl)-1H-pyrrole, C13H24N2O2Si (I), and 2,4-dinitropyrrole. In the solid state, I exists as discrete mols. with only weak C-H...nitro H bonds between them. Crystallog. data are given.

AB - The nitration of 1-(triisopropylsilyl)-1H-pyrrole leads to a mixt. of products following partial acid cleavage of the triisopropylsilyl protecting group. Structural detn. showed the isolated products to be 3-nitro-1-(triisopropylsilyl)-1H-pyrrole, C13H24N2O2Si (I), and 2,4-dinitropyrrole. In the solid state, I exists as discrete mols. with only weak C-H...nitro H bonds between them. Crystallog. data are given.

KW - nitration

KW - 4-dinitropyrrole

KW - hydrogen bonds

U2 - 10.1107/S1600536806025943

DO - 10.1107/S1600536806025943

M3 - Article

SN - 1600-5368

VL - 62

SP - o3282-o3284

JO - Acta Crystallographica Section E: Structure Reports

JF - Acta Crystallographica Section E: Structure Reports

IS - 8

ER -

3-Nitro-1-(triisopropylsilyl)-1H-pyrrole

Abstract

Keywords

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