2,4,6-Trinitrophenyl furan-2-carboxylate

Rodolfo Moreno-Fuquen, Fabricio Mosquera, Alan R Kennedy

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title carboxyl-ate derivative, C11H5N3O9, the picryl ring forms an angle of 75.79 (7)° with the ester fragment, indicating a near perpendicular disposition. The nitro substituents are variously oriented with respect to the picryl ring [dihedral angles = 3.22 (10), 16.03 (12) and 36.63 (10)°]. In the crystal, mol-ecules form helical chains sustained by C-H⋯O inter-actions along [010]. The furanyl residue is disordered, having two coplanar slightly displaced orientations [major component = 0.730 (9)].

Original languageEnglish
Article numbero1682
Number of pages1
JournalActa Crystallographica Section E: Structure Reports
Volume69
Issue number11
DOIs
Publication statusPublished - 23 Oct 2013

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furans
Dihedral angle
carboxylates
Esters
Derivatives
Crystals
rings
dihedral angle
esters
fragments
crystals
2-furoic acid

Keywords

  • crystals
  • molecules
  • picryl ring

Cite this

Moreno-Fuquen, Rodolfo ; Mosquera, Fabricio ; Kennedy, Alan R. / 2,4,6-Trinitrophenyl furan-2-carboxylate. In: Acta Crystallographica Section E: Structure Reports. 2013 ; Vol. 69, No. 11.
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2,4,6-Trinitrophenyl furan-2-carboxylate. / Moreno-Fuquen, Rodolfo; Mosquera, Fabricio; Kennedy, Alan R.

In: Acta Crystallographica Section E: Structure Reports, Vol. 69, No. 11, o1682, 23.10.2013.

Research output: Contribution to journalArticle

TY - JOUR

T1 - 2,4,6-Trinitrophenyl furan-2-carboxylate

AU - Moreno-Fuquen, Rodolfo

AU - Mosquera, Fabricio

AU - Kennedy, Alan R

PY - 2013/10/23

Y1 - 2013/10/23

N2 - In the title carboxyl-ate derivative, C11H5N3O9, the picryl ring forms an angle of 75.79 (7)° with the ester fragment, indicating a near perpendicular disposition. The nitro substituents are variously oriented with respect to the picryl ring [dihedral angles = 3.22 (10), 16.03 (12) and 36.63 (10)°]. In the crystal, mol-ecules form helical chains sustained by C-H⋯O inter-actions along [010]. The furanyl residue is disordered, having two coplanar slightly displaced orientations [major component = 0.730 (9)].

AB - In the title carboxyl-ate derivative, C11H5N3O9, the picryl ring forms an angle of 75.79 (7)° with the ester fragment, indicating a near perpendicular disposition. The nitro substituents are variously oriented with respect to the picryl ring [dihedral angles = 3.22 (10), 16.03 (12) and 36.63 (10)°]. In the crystal, mol-ecules form helical chains sustained by C-H⋯O inter-actions along [010]. The furanyl residue is disordered, having two coplanar slightly displaced orientations [major component = 0.730 (9)].

KW - crystals

KW - molecules

KW - picryl ring

U2 - 10.1107/S1600536813028274

DO - 10.1107/S1600536813028274

M3 - Article

VL - 69

JO - Acta Crystallographica Section E: Structure Reports

JF - Acta Crystallographica Section E: Structure Reports

SN - 1600-5368

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M1 - o1682

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