1,4-pentadienyl-3-sulfonamides: Frameworks for disfavored radical cascade cyclizations

Sacha Bommezijn, Concepcion Gonzalez Martin, Alan R. Kennedy, Dimitrios Lizos, John A. Murphy

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

1,4-Pentadienyl-3-sulfonamides afford products including those resulting from disfavored 5-endo-trig reactions when subjected to radical cyclization conditions. Products resulting from pathways featuring 4-exo-trig cyclizations are also detected, even when the 4-exo-trig reaction leads to a highly strained bicyclo[3.2.0] ring system.
Original languageEnglish
Pages (from-to)3405-3407
Number of pages2
JournalOrganic Letters
Volume3
Issue number21
DOIs
Publication statusPublished - 21 Sep 2001

Keywords

  • 1
  • 4-Pentadienyl-3-sulfonamides
  • 5-endo-trig reactions
  • 4-exo-trig cyclizations
  • ring system

Fingerprint Dive into the research topics of '1,4-pentadienyl-3-sulfonamides: Frameworks for disfavored radical cascade cyclizations'. Together they form a unique fingerprint.

  • Cite this