Structural studies of cesium, lithium/cesium and sodium/cesium bis(trimethylsilyl)amide (HMDS) complexes

  • Charles O'Hara (Creator)
  • Antonio Martinez-Martinez (Creator)
  • Ana Isabel Ojeda Amador (Creator)
  • Alan Kennedy (Creator)



The data set contains two MS word documents containing supplementary information (one for X-ray crystallographic data, the other NMR spectroscopic data) and supports the related research publication.

In the paper a new method for preparing CsHMDS is reported. In addition, the structures and syntheses of two polymeric mixed alkali metal HMDS complexes are detailed. Finally, the structural chemistry (solid- and solution-state) of CsHMDS with different multidentate donors is described.
Date made available4 May 2016
PublisherUniversity of Strathclyde

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