Revealing the remarkable structural diversity of the alkali metal transfer agents of the trans-calix[2]benzene[2]pyrrolidide ligand

  • Robert Mulvey (Creator)
  • Maria Angeles Fuentes-Dominguez (Contributor)
  • Antonio Martinez-Martinez (Contributor)
  • Alan Kennedy (Contributor)

Dataset

Description

The data set contains four files. These data relate to the research discussed in the manuscript “Revealing the remarkable structural diversity of the alkali metal transfer agents of the trans-calix[2]benzene[2]pyrrolidide ligand”. Corresponding authors: M. Ángeles Fuentes, Antonio J. Martínez-Martínez, Alan R. Kennedy and Robert E. Mulvey*.

This work was made possible through generous financial support from the EPSRC for the project “A co-operative bimetallic approach for the transformation of lithiation” (award no. EP/K001183/1) and the Royal Society (Wolfson research merit award to R.E.M). PI: Professor R. E. Mulvey; PDRA: Dr M. Á. Fuentes.

This manuscript advances alkali metal chemistry of the trans-calix[2]benzene[2]pyrrolidide ligand showing a remarkable structural diversity. These novel complexes can be consider very important as alkali metal ligand transfer agents for organoactinide and organolanthaide chemistry. All complexes have been characterized by X-ray crystallography, NMR spectroscopy and elemental analysis.


Files present:
1. General procedures
2. NMR spectroscopy and elemental analysis
3. X-Ray crystallographic structures
4. CIF for the crystallographic structures

Please, note that to view the cif files it is necessary to use a graphical program which can open crystallography files (programs such as Mercury, ORTEP-3, etc).
Date made available2016
PublisherUniversity of Strathclyde
Date of data production2015 - 2016

Cite this

Mulvey, R. (Creator), Fuentes-Dominguez, M. A. (Contributor), Martinez-Martinez, A. (Contributor), Kennedy, A. (Contributor). (2016). Revealing the remarkable structural diversity of the alkali metal transfer agents of the trans-calix[2]benzene[2]pyrrolidide ligand. University of Strathclyde. 1(.docx), 2(.docx), 3(.docx), combined_structures_1_to_6(.cif). 10.15129/dbceecc0-96d3-4f75-a7eb-a08eaa77b063