Data for "Investigation of (mis-)orientation in zincblende GaN grown on micro-patterned Si(001) using electron backscatter diffraction"

Dataset

Description

This dataset provides the experimental data used to generate the figures in the paper entitled "Investigation of (mis-)orientation in zincblende GaN grown on micro-patterned Si(001) using electron backscatter diffraction".

Electron backscatter diffraction (EBSD) measurements were performed using a Nordlys and Symmetry S2 EBSD detector from Oxford Instruments attached to an FEI Quanta 250 and Versa 3D field emission scanning electron microscope (SEM), respectively. The EBSD data was acquired at 20 kV and at a sample tilt of 70° with respect to the normal of the incident electron beam.

Abstract of the paper:
We present the application of electron backscatter diffraction (EBSD) as a technique for characterising wurtzite (wz) and zincblende (zb) polytypes of GaN grown upon micropatterned Si (001) substrates. The Si substrate is etched to create parallel V-shaped grooves with opposing {111} facets before the deposition of GaN. EBSD revealed that wz-GaN growth fronts initially form on the {111} Si facets before undergoing a transition from a wurtzite to zincblende structure as the two growth fronts meet. Orientation analysis of the GaN structures revealed that the wz-GaN growth fronts had different growth orientations but shared the same crystallographic relationship with the zb-GaN, such that perp{30-38}_wz || <110>_zb, <11-20>_wz || <110>_zb and perp{30-34}_wz || <001>_zb. Furthermore, the crystallographic relationship, {0001}_wz-GaN || {111}_zb-GaN || {111}_Si, and alignment of the wz- and zb-GaN with respect to the Si substrate was investigated. The two wz-GaN <0001> growth directions were expected to coalesce at an angle of 109.5 degree, however measurements revealed an angle of 108 degree. The resultant misalignment of 1.5degree induces misorientation in the zb-GaN crystal lattice. While the degree of misorientation within the zb-GaN lattice is low, < 1 degree, the zb-GaN lattice is deformed and bends towards the wz-GaN interfaces about the specimen direction parallel to the length of the V-groove. Further EBSD measurements over larger areas of the sample revealed that these results were consistent across the sample. However, it was also revealed that additional factors induce changes in the orientation of the zb-GaN lattice, which may relate to the initial growth conditions of the zb-GaN.
Date made available7 Jan 2025
PublisherUniversity of Strathclyde

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